Passivation by pyridine-induced PbI2in methylammonium lead iodide perovskites

Andre Cook; Timothy W. Jones; Jacob Tse Wei Wang; Hua Li; Rob Atkin; Noel W. Duffy; Scott W. Donne; Gregory J. Wilson

doi:10.1039/d0ra04641h

Passivation by pyridine-induced PbI₂in methylammonium lead iodide perovskites

Andre Cook, Timothy W. Jones, Jacob Tse Wei Wang, Hua Li, Rob Atkin, Noel W. Duffy, Scott W. Donne, Gregory J. Wilson

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Defects at discontinuities of the perovskite lattice limit the performance of the perovskite solar cell (PSC). Lead iodide (PbI2) and pyridine have been shown to passivate these defects. We treat methylammonium lead iodide (MAPbI3) films with pyridine solutions to investigate the effects of the two passivators. By comparing confocal fluorescence microscopy (CFM) images at 405 nm excitation and then at 559 nm excitation we demonstrate the pyridine treatment passivates and forms PbI2 crystallites which cause additional passivation. This journal is

Original language	English
Pages (from-to)	23829-23833
Number of pages	5
Journal	RSC Advances
Volume	10
Issue number	40
DOIs	https://doi.org/10.1039/d0ra04641h
Publication status	Published - 23 Jun 2020

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title = "Passivation by pyridine-induced PbI2in methylammonium lead iodide perovskites",

abstract = "Defects at discontinuities of the perovskite lattice limit the performance of the perovskite solar cell (PSC). Lead iodide (PbI2) and pyridine have been shown to passivate these defects. We treat methylammonium lead iodide (MAPbI3) films with pyridine solutions to investigate the effects of the two passivators. By comparing confocal fluorescence microscopy (CFM) images at 405 nm excitation and then at 559 nm excitation we demonstrate the pyridine treatment passivates and forms PbI2 crystallites which cause additional passivation. This journal is ",

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doi = "10.1039/d0ra04641h",

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T1 - Passivation by pyridine-induced PbI2in methylammonium lead iodide perovskites

AU - Cook, Andre

AU - Jones, Timothy W.

AU - Wang, Jacob Tse Wei

AU - Li, Hua

AU - Atkin, Rob

AU - Duffy, Noel W.

AU - Donne, Scott W.

AU - Wilson, Gregory J.

PY - 2020/6/23

Y1 - 2020/6/23

N2 - Defects at discontinuities of the perovskite lattice limit the performance of the perovskite solar cell (PSC). Lead iodide (PbI2) and pyridine have been shown to passivate these defects. We treat methylammonium lead iodide (MAPbI3) films with pyridine solutions to investigate the effects of the two passivators. By comparing confocal fluorescence microscopy (CFM) images at 405 nm excitation and then at 559 nm excitation we demonstrate the pyridine treatment passivates and forms PbI2 crystallites which cause additional passivation. This journal is

AB - Defects at discontinuities of the perovskite lattice limit the performance of the perovskite solar cell (PSC). Lead iodide (PbI2) and pyridine have been shown to passivate these defects. We treat methylammonium lead iodide (MAPbI3) films with pyridine solutions to investigate the effects of the two passivators. By comparing confocal fluorescence microscopy (CFM) images at 405 nm excitation and then at 559 nm excitation we demonstrate the pyridine treatment passivates and forms PbI2 crystallites which cause additional passivation. This journal is

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U2 - 10.1039/d0ra04641h

DO - 10.1039/d0ra04641h

M3 - Article

AN - SCOPUS:85087675301

SN - 2046-2069

VL - 10

SP - 23829

EP - 23833

JO - RSC Advances

JF - RSC Advances

IS - 40

ER -

Passivation by pyridine-induced PbI₂in methylammonium lead iodide perovskites

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