Part One. Silver and ruthenium complexes of N-heterocyclic carbene linked cyclophanes Part Two. The total synthesis and elucidation of Samoquasine A

Jesse Reuben Parkin-Gibbs

doi:10.26182/5e79a24862280

Part One. Silver and ruthenium complexes of N-heterocyclic carbene linked cyclophanes Part Two. The total synthesis and elucidation of Samoquasine A

Jesse Reuben Parkin-Gibbs

School of Molecular Sciences

Research output: Thesis › Doctoral Thesis

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Abstract

This thesis is broken into two main projects. Part One, completed under Professor Baker, details the synthesis and properties of transition metal complexes bearing N-heterocyclic carbene ligands. Several complexes were isolated, including a novel n6-bound, ruthenium-NHC complex. Its structural, biological and catalytic characteristics have been explored, with mild catalytic activity found. Part Two, completed under the supervision of Associate Professor Piggott, details the synthesis and structural elucidation of the natural product 'samoquasine A'. Herein, the true identity of samoquasine A was investigated, and unequivocally proven to be perlolidine. This work currently represents the most efficient synthesis of perlolidine to date.

Original language	English
Qualification	Doctor of Philosophy
Awarding Institution	The University of Western Australia
Supervisors/Advisors	Baker, Murray, Supervisor Piggott, Matthew, Supervisor
Thesis sponsors	Australian Government Research Training Program
Award date	11 Feb 2018
DOIs	https://doi.org/10.26182/5e79a24862280
Publication status	Unpublished - 2018

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Embargoed from 13/03/2018 to 13/03/2020. Made publicly available on 13/03/2020.

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10.26182/5e79a24862280

THESIS - DOCTOR OF PHILOSOPHY - PARKIN-GIBBS Jesse Reuben - 2018
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title = "Part One. Silver and ruthenium complexes of N-heterocyclic carbene linked cyclophanes Part Two. The total synthesis and elucidation of Samoquasine A",

abstract = "This thesis is broken into two main projects. Part One, completed under Professor Baker, details the synthesis and properties of transition metal complexes bearing N-heterocyclic carbene ligands. Several complexes were isolated, including a novel n6-bound, ruthenium-NHC complex. Its structural, biological and catalytic characteristics have been explored, with mild catalytic activity found. Part Two, completed under the supervision of Associate Professor Piggott, details the synthesis and structural elucidation of the natural product 'samoquasine A'. Herein, the true identity of samoquasine A was investigated, and unequivocally proven to be perlolidine. This work currently represents the most efficient synthesis of perlolidine to date. ",

keywords = "inorganic syntheses, NHC-metal complex, Ruthenium NHC complex, silver NHC complexes, organic syntheses, total synthesis, Natural product synthesis, Organometallic",

author = "Parkin-Gibbs, {Jesse Reuben}",

year = "2018",

doi = "10.26182/5e79a24862280",

language = "English",

school = "The University of Western Australia",

}

TY - BOOK

T1 - Part One. Silver and ruthenium complexes of N-heterocyclic carbene linked cyclophanes Part Two. The total synthesis and elucidation of Samoquasine A

AU - Parkin-Gibbs, Jesse Reuben

PY - 2018

Y1 - 2018

N2 - This thesis is broken into two main projects. Part One, completed under Professor Baker, details the synthesis and properties of transition metal complexes bearing N-heterocyclic carbene ligands. Several complexes were isolated, including a novel n6-bound, ruthenium-NHC complex. Its structural, biological and catalytic characteristics have been explored, with mild catalytic activity found. Part Two, completed under the supervision of Associate Professor Piggott, details the synthesis and structural elucidation of the natural product 'samoquasine A'. Herein, the true identity of samoquasine A was investigated, and unequivocally proven to be perlolidine. This work currently represents the most efficient synthesis of perlolidine to date.

AB - This thesis is broken into two main projects. Part One, completed under Professor Baker, details the synthesis and properties of transition metal complexes bearing N-heterocyclic carbene ligands. Several complexes were isolated, including a novel n6-bound, ruthenium-NHC complex. Its structural, biological and catalytic characteristics have been explored, with mild catalytic activity found. Part Two, completed under the supervision of Associate Professor Piggott, details the synthesis and structural elucidation of the natural product 'samoquasine A'. Herein, the true identity of samoquasine A was investigated, and unequivocally proven to be perlolidine. This work currently represents the most efficient synthesis of perlolidine to date.

KW - inorganic syntheses

KW - NHC-metal complex

KW - Ruthenium NHC complex

KW - silver NHC complexes

KW - organic syntheses

KW - total synthesis

KW - Natural product synthesis

KW - Organometallic

U2 - 10.26182/5e79a24862280

DO - 10.26182/5e79a24862280

M3 - Doctoral Thesis

ER -

Part One. Silver and ruthenium complexes of N-heterocyclic carbene linked cyclophanes Part Two. The total synthesis and elucidation of Samoquasine A

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