Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate

O. Mallow, J. Bolsinger, P. Finke, M. Hesse, Y. Chen, A. Duthie, Simon Grabowsky, P. Luger, S. Mebs, J. Beckmann

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Abstract

The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. © 2014 American Chemical Society.
Original languageEnglish
Pages (from-to)10870-10873
JournalJournal of the American Chemical Society
Volume136
Issue number31
Early online date25 Jul 2014
DOIs
Publication statusPublished - Aug 2014

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