Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate

O. Mallow; J. Bolsinger; P. Finke; M. Hesse; Y. Chen; A. Duthie; Simon Grabowsky; P. Luger; S. Mebs; J. Beckmann

doi:10.1021/ja505648x

Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate

O. Mallow, J. Bolsinger, P. Finke, M. Hesse, Y. Chen, A. Duthie, Simon Grabowsky, P. Luger, S. Mebs, J. Beckmann

School of Molecular Sciences

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Abstract

The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. © 2014 American Chemical Society.

Original language	English
Pages (from-to)	10870-10873
Journal	Journal of the American Chemical Society
Volume	136
Issue number	31
Early online date	25 Jul 2014
DOIs	https://doi.org/10.1021/ja505648x
Publication status	Published - Aug 2014

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10.1021/ja505648x

Mallow et al Oxygen Transfer from an Intramolecularly Coordinated Di-aryltellurium Oxide (2014)Accepted author manuscript, 406 KB

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Mallow, O., Bolsinger, J., Finke, P., Hesse, M., Chen, Y., Duthie, A., Grabowsky, S., Luger, P., Mebs, S., & Beckmann, J. (2014). Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate. Journal of the American Chemical Society, 136(31), 10870-10873. https://doi.org/10.1021/ja505648x

Mallow, O. ; Bolsinger, J. ; Finke, P. ; Hesse, M. ; Chen, Y. ; Duthie, A. ; Grabowsky, Simon ; Luger, P. ; Mebs, S. ; Beckmann, J. / Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate. In: Journal of the American Chemical Society. 2014 ; Vol. 136, No. 31. pp. 10870-10873.

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title = "Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate",

abstract = "The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. {\textcopyright} 2014 American Chemical Society.",

author = "O. Mallow and J. Bolsinger and P. Finke and M. Hesse and Y. Chen and A. Duthie and Simon Grabowsky and P. Luger and S. Mebs and J. Beckmann",

year = "2014",

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Mallow, O, Bolsinger, J, Finke, P, Hesse, M, Chen, Y, Duthie, A, Grabowsky, S, Luger, P, Mebs, S & Beckmann, J 2014, 'Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate', Journal of the American Chemical Society, vol. 136, no. 31, pp. 10870-10873. https://doi.org/10.1021/ja505648x

Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate. / Mallow, O.; Bolsinger, J.; Finke, P.; Hesse, M.; Chen, Y.; Duthie, A.; Grabowsky, Simon; Luger, P.; Mebs, S.; Beckmann, J.

In: Journal of the American Chemical Society, Vol. 136, No. 31, 08.2014, p. 10870-10873.

Research output: Contribution to journal › Article

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AU - Mallow, O.

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AU - Finke, P.

AU - Hesse, M.

AU - Chen, Y.

AU - Duthie, A.

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AU - Luger, P.

AU - Mebs, S.

AU - Beckmann, J.

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AB - The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. © 2014 American Chemical Society.

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