Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers

R.L. Roberts; T. Schwich; T.C. Corkery; M.P. Cifuentes; K.A. Green; J.D. Farmer; Paul Low; T.B. Marder; M. Samoc; M.G. Humphrey

doi:10.1002/adma.200803669

Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers

R.L. Roberts, T. Schwich, T.C. Corkery, M.P. Cifuentes, K.A. Green, J.D. Farmer, Paul Low, T.B. Marder, M. Samoc, M.G. Humphrey

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

77 Citations (Scopus)

Abstract

An alkynylruthenium dendrimer exhibits two-photon absorption behavior below 1000 nm, and a nonlinear increase in nonlinearity upon dendrimer growth. Beyond 1000 nm, it undergoes 3PA-induced photochemistry. Its nonlinear optical performance is an order of magnitude greater than that of similar organic dendrimers, demonstrating the performance enhancement possible upon incorporation of metal centers into a molecular architecture.

Original language	English
Pages (from-to)	2318-2322
Journal	Advanced Materials
Volume	21
Early online date	25 Mar 2009
DOIs	https://doi.org/10.1002/adma.200803669
Publication status	Published - 12 Jun 2009

Access to Document

10.1002/adma.200803669

Cite this

Roberts, R. L., Schwich, T., Corkery, T. C., Cifuentes, M. P., Green, K. A., Farmer, J. D., Low, P., Marder, T. B., Samoc, M., & Humphrey, M. G. (2009). Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers. Advanced Materials, 21, 2318-2322. https://doi.org/10.1002/adma.200803669

@article{61022fc5c9904a49b99a75a275ae6c5f,

title = "Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers",

abstract = "An alkynylruthenium dendrimer exhibits two-photon absorption behavior below 1000 nm, and a nonlinear increase in nonlinearity upon dendrimer growth. Beyond 1000 nm, it undergoes 3PA-induced photochemistry. Its nonlinear optical performance is an order of magnitude greater than that of similar organic dendrimers, demonstrating the performance enhancement possible upon incorporation of metal centers into a molecular architecture. ",

author = "R.L. Roberts and T. Schwich and T.C. Corkery and M.P. Cifuentes and K.A. Green and J.D. Farmer and Paul Low and T.B. Marder and M. Samoc and M.G. Humphrey",

year = "2009",

month = jun,

day = "12",

doi = "10.1002/adma.200803669",

language = "English",

volume = "21",

pages = "2318--2322",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",

}

Roberts, RL, Schwich, T, Corkery, TC, Cifuentes, MP, Green, KA, Farmer, JD, Low, P, Marder, TB, Samoc, M & Humphrey, MG 2009, 'Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers', Advanced Materials, vol. 21, pp. 2318-2322. https://doi.org/10.1002/adma.200803669

TY - JOUR

T1 - Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers

AU - Roberts, R.L.

AU - Schwich, T.

AU - Corkery, T.C.

AU - Cifuentes, M.P.

AU - Green, K.A.

AU - Farmer, J.D.

AU - Low, Paul

AU - Marder, T.B.

AU - Samoc, M.

AU - Humphrey, M.G.

PY - 2009/6/12

Y1 - 2009/6/12

N2 - An alkynylruthenium dendrimer exhibits two-photon absorption behavior below 1000 nm, and a nonlinear increase in nonlinearity upon dendrimer growth. Beyond 1000 nm, it undergoes 3PA-induced photochemistry. Its nonlinear optical performance is an order of magnitude greater than that of similar organic dendrimers, demonstrating the performance enhancement possible upon incorporation of metal centers into a molecular architecture.

AB - An alkynylruthenium dendrimer exhibits two-photon absorption behavior below 1000 nm, and a nonlinear increase in nonlinearity upon dendrimer growth. Beyond 1000 nm, it undergoes 3PA-induced photochemistry. Its nonlinear optical performance is an order of magnitude greater than that of similar organic dendrimers, demonstrating the performance enhancement possible upon incorporation of metal centers into a molecular architecture.

U2 - 10.1002/adma.200803669

DO - 10.1002/adma.200803669

M3 - Article

VL - 21

SP - 2318

EP - 2322

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

ER -

Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers

Abstract

Access to Document

Fingerprint

Cite this