Organic alloys of room temperature liquids thiophenol and selenophenol

Sajesh Thomas, R. Sathishkumar, T.N. Guru Row

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

This journal is © The Royal Society of Chemistry. The first examples of organic alloys of two room temperature liquids, obtained and characterized via in situ cryo-crystallography, are presented. Thiophenol and selenophenol, which exhibit isostructurality and similar modes of S·S and Se·Se homo-chalcogen interactions along with weak and rare S-H·S and Se-H·Se hydrogen bonds, are shown to form solid solutions exhibiting Veggard's law-like trends.
Original languageEnglish
Pages (from-to)14255-14258
JournalChemical Communications
Volume51
Issue number75
DOIs
Publication statusPublished - 2015

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