Octapi Interactions : Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions

J. Lu; D.R. Turner; L.P. Harding; Lindsay Byrne; Murray Baker; S.R. Batten

doi:10.1021/ja9041912

Octapi Interactions : Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions

J. Lu, D.R. Turner, L.P. Harding, Lindsay Byrne, Murray Baker, S.R. Batten

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.

Original language	English
Pages (from-to)	10372-10373
Journal	Journal of American Chemical Society
Volume	131
DOIs	https://doi.org/10.1021/ja9041912
Publication status	Published - 2009

Access to Document

10.1021/ja9041912

Cite this

@article{21e08495393f464baa40c43b68906781,

title = "Octapi Interactions : Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions",

abstract = "An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.",

author = "J. Lu and D.R. Turner and L.P. Harding and Lindsay Byrne and Murray Baker and S.R. Batten",

year = "2009",

doi = "10.1021/ja9041912",

language = "English",

volume = "131",

pages = "10372--10373",

journal = "Journal of American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Octapi Interactions : Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions

AU - Lu, J.

AU - Turner, D.R.

AU - Harding, L.P.

AU - Byrne, Lindsay

AU - Baker, Murray

AU - Batten, S.R.

PY - 2009

Y1 - 2009

N2 - An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.

AB - An unprecedented 2.5 nm array of π interactions between eight aromatic rings drives the formation of a [2]catenane. Disruption of this array through the use of longer ligands results in the formation of only single, uncatenated rings. The catenated complex is shown to persist in solution alongside its constituent metallomacrocycles.

U2 - 10.1021/ja9041912

DO - 10.1021/ja9041912

M3 - Article

C2 - 19722615

SN - 0002-7863

VL - 131

SP - 10372

EP - 10373

JO - Journal of American Chemical Society

JF - Journal of American Chemical Society

ER -

Octapi Interactions : Self-Assembly of a Pd-Based [2]Catenane Driven by Eightfold π Interactions

Abstract

Access to Document

Fingerprint

Cite this