TY - JOUR
T1 - Novel Coordination Complexes in the Bismuth(III)/Oxinate System
AU - Campi, E.M.
AU - Deacon, G.B.
AU - Jackson, W.R.
AU - Skelton, Brian
AU - Smith, K.A.
AU - White, Allan
PY - 2006
Y1 - 2006
N2 - Single crystal structural characterizations are reported for a pair of bismuth(III)/oxinate ('ox') complexes, formulated as [Bi(ox)(3)(OH2)](2) and [BiPh(ox)(2)(O-dmso)](2) respectively In the former, analytically significant, species the Bi(ox)(3) coordination sphere is augmented by dimerization by way of bridging interactions through two of the ox oxygen donor atoms and a residue modelled as a coordinated water molecule oxygen atom. In the dmso complex, a novel pentagonal pyramidal coordination environment (Ph at the apex) is described, presumably consequent on the effect of close eta(6)-interactions of the bismuth with the carbocyclic ring of one of the ox ligands of an adjacent, inversion-related molecule.
AB - Single crystal structural characterizations are reported for a pair of bismuth(III)/oxinate ('ox') complexes, formulated as [Bi(ox)(3)(OH2)](2) and [BiPh(ox)(2)(O-dmso)](2) respectively In the former, analytically significant, species the Bi(ox)(3) coordination sphere is augmented by dimerization by way of bridging interactions through two of the ox oxygen donor atoms and a residue modelled as a coordinated water molecule oxygen atom. In the dmso complex, a novel pentagonal pyramidal coordination environment (Ph at the apex) is described, presumably consequent on the effect of close eta(6)-interactions of the bismuth with the carbocyclic ring of one of the ox ligands of an adjacent, inversion-related molecule.
U2 - 10.1002/zaac.200600045
DO - 10.1002/zaac.200600045
M3 - Article
SN - 0044-2313
VL - 632
SP - 1483
EP - 1486
JO - Zeitschrift fuer Anorganische und Allgemeine Chemie
JF - Zeitschrift fuer Anorganische und Allgemeine Chemie
ER -