Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Mohamed Makha; Alexandre Sobolev; Colin Raston

doi:10.1039/b513543e

Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Mohamed Makha
, Alexandre Sobolev
, Colin Raston

Research output: Contribution to journal › Article › peer-review

32 Citations (Web of Science)

Abstract

Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)(5-)/Na+/Yb3+.

Original language	English
Pages (from-to)	57-59
Journal	Chemical Communications
Volume	1
DOIs	https://doi.org/10.1039/b513543e
Publication status	Published - 2006

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title = "Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene",

abstract = "Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)(5-)/Na+/Yb3+.",

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AU - Sobolev, Alexandre

AU - Raston, Colin

PY - 2006

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AB - Reaction of equimolar amounts of sodium para-sulfonato-calix[4]arene, tetraphenylphosphonium chloride and ytterbium chloride in water results in the formation of a mineral clay-like structure, where the hydrophobic tetraphenylphosphonium cations interpose a bilayer arrangement based on a 2D coordination polymer of (calix[4]arene)(5-)/Na+/Yb3+.

U2 - 10.1039/b513543e

DO - 10.1039/b513543e

M3 - Article

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VL - 1

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JO - Chemical Communications

JF - Chemical Communications

ER -

Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

Abstract

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