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Abstract
A nickel-catalyzed tetradehydro-Diels-Alder reaction of (E)-3-ene-1,8-diynes for the preparation of isoindolines, dihydroisobenzofurans, and tetrahydroisoquinolines has been developed. A series of air-stable nickel catalysts were used in this study, including the novel nickel(0)-phosphite catalysts, Ni[P(O-3,5-Me-Ph)3]4, Ni[P(O-1-naphthyl)3]4, and Ni[P(O-2-naphthyl)3]4. To help understand the type of intermediate in the initial cycloisomerization process, the trapping of nickellacycle intermediates with pinacolborane to yield vinyl boronates is also discussed.
Original language | English |
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Pages (from-to) | 5391-5402 |
Number of pages | 12 |
Journal | Journal of Organic Chemistry |
Volume | 88 |
Issue number | 9 |
DOIs | |
Publication status | Published - 5 May 2023 |
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Dive into the research topics of 'Nickel Phosphite-Catalyzed Tetradehydro-Diels-Alder Reactions of (E)-3-ene-1,8-diynes'. Together they form a unique fingerprint.Projects
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Fill it, Squeeze it, Crush it: Extreme Gas Uptake in Microporous Materials
Moggach, S. (Investigator 01)
ARC Australian Research Council
1/10/20 → 30/09/24
Project: Research