© 2014 Elsevier Ltd. The two Clearwater Lake impact structures (Québec, Canada) are generally interpreted as a crater doublet formed by the impact of a binary asteroid. Here, arguments are presented that raise important questions about the proposed double impact scenario. New 40Ar/39Ar dating of two virtually fresh impact melt rock samples from the ≥36km West Clearwater Lake impact structure yielded two statistically robust Early Permian plateau ages with a weighted mean of 286.2±2.2 (2.6) Ma (2σ; MSWD=0.33; P=0.57). In contrast, 40Ar/39Ar results for two chloritized melt rocks from the ~26km East Clearwater Lake impact structure produced disturbed age spectra suggestive of a distinct extraneous argon component. Although individually weakly robust, age spectra corrected for the trapped argon component and inverse isochron plots for the East Clearwater melt rocks consistently yielded apparent ages around ~460-470Ma. No Permian signal was found in either of these melt aliquots. Our new 40Ar/39Ar results reproduce earlier 40Ar/39Ar plateau ages (~283Ma and ~465Ma, respectively) for the two impact structures by Bottomley et al. (1990) and are in conflict with a previous, statistically non-robust Rb-Sr age of 287 ±26Ma for East Clearwater. The combined cluster of apparent ages of ~460-470Ma, derived from four different samples across the impact melt sheet, is very unlikely to represent a 'false age effect' due to the incorporation of extraneous argon into the melt; instead, it strongly favors a Middle Ordovician age for the East Clearwater impact and impact-induced hydrothermal chloritization. Moreover, the Clearwater impact structures are characterized by different natural remanent magnetizations testifying to separate geologic histories, an effect unexpected in the case of a Permian double impact. Whereas the West Clearwater impact affected Ordovician carbonates incorporated into the impact breccia, drill core reports from the 1960s concluded that clasts of Ordovician sedimentary rocks are seemingly absent in the impact breccia lens of the East Clearwater Lake impact structure, which is overlain by >100m of post-impact sandstones, shales and carbonates. No resolvable impactor contamination has so far been detected in the West Clearwater impact melt rocks, whereas East Clearwater carries a distinct ordinary (possibly L-) chondritic impactor signature in its melt rocks. East Clearwater Lake might thus represent one among a long list of Ordovician impact structures in North America and northern Europe that were presumably formed in response to the L-chondrite asteroid breakup event ~470Ma ago. Paleogeographic reconstructions show that the Ordovician East Clearwater impact probably occurred in a near-coastal to shallow marine setting, while the Permian West Clearwater impact hit continental Pangaea. Along with the new 40Ar/39Ar data, the paleomagnetic, sedimentologic, and geochemical findings suggest that the close spatial arrangement of the two Clearwater Lakes is most likely pure coincidence. The two impact structures seem to represent a 'false doublet' struck by impacts separated by ~180 million years in time. The new results for the Clearwater Lake impact structures have major implications for the reliable identification of doublet impact craters and the rate of binary asteroid impacts on Earth and on other planetary bodies in the inner Solar System.