Nanocage Encapsulation of Two ortho-Carborane Molecules

Colin Raston, G.W.V. Cave

Research output: Contribution to journalArticlepeer-review

41 Citations (Scopus)

Abstract

Bowl-shaped C-methylcalix[4]resorcinarene forms a 1:1 ball-and-socket nanostructure with o-carborane through two endo-cavity BC[BOND]H⋅⋅⋅π hydrogen bonds. In the presence of 4′,2:6,4′′-terpyridine, two of these nanostructures are held together by four terpyridines through sixteen OH⋅⋅⋅N hydrogen bonds, completely shrouding two carboranes.
Original languageEnglish
Pages (from-to)279-282
JournalChemistry - A European Journal
Volume10
Issue number1
DOIs
Publication statusPublished - 2004

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