Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe3)L2(η-C7H7)]•+ (L2 = 2,2′-bipyridine or dppe)

N.J. Brown; D. Collison; R. Edge; E.C. Fitzgerald; Paul Low; M. Helliwell; Y.T. Ta; M.W. Whiteley

doi:10.1039/b924759a

Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe₃)L₂(η-C₇H₇)]^•+(L₂ = 2,2′-bipyridine or dppe)

N.J. Brown, D. Collison, R. Edge, E.C. Fitzgerald, Paul Low, M. Helliwell, Y.T. Ta, M.W. Whiteley

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The unprecedented spectroscopic and structural characterisation of a series of 17-electron, monometallic diynyl radicals, [Mo(C≡C–C≡CR)L2(η-C7H7)]˙+ (L2 = bipy, R = SiMe3; L2 = dppe, R = SiMe3 or H), are reported; the (L2 = dppe, R = SiMe3) derivative is reactive to chain-centred Cβ–Cβ′ dimerisation.

Original language	English
Pages (from-to)	2253-2255
Journal	Chemical Communications
Volume	46
Issue number	13
Early online date	19 Jan 2010
DOIs	https://doi.org/10.1039/b924759a
Publication status	Published - 7 Apr 2010

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10.1039/b924759a

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title = "Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe3)L2(η-C7H7)]•+ (L2 = 2,2′-bipyridine or dppe)",

abstract = "The unprecedented spectroscopic and structural characterisation of a series of 17-electron, monometallic diynyl radicals, [Mo(C≡C–C≡CR)L2(η-C7H7)]˙+ (L2 = bipy, R = SiMe3; L2 = dppe, R = SiMe3 or H), are reported; the (L2 = dppe, R = SiMe3) derivative is reactive to chain-centred Cβ–Cβ′ dimerisation.",

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Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe₃)L₂(η-C₇H₇)]^•+(L₂ = 2,2′-bipyridine or dppe). / Brown, N.J.; Collison, D.; Edge, R.; Fitzgerald, E.C.; Low, Paul; Helliwell, M.; Ta, Y.T.; Whiteley, M.W.

In: Chemical Communications, Vol. 46, No. 13, 07.04.2010, p. 2253-2255.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe3)L2(η-C7H7)]•+ (L2 = 2,2′-bipyridine or dppe)

AU - Brown, N.J.

AU - Collison, D.

AU - Edge, R.

AU - Fitzgerald, E.C.

AU - Low, Paul

AU - Helliwell, M.

AU - Ta, Y.T.

AU - Whiteley, M.W.

PY - 2010/4/7

Y1 - 2010/4/7

N2 - The unprecedented spectroscopic and structural characterisation of a series of 17-electron, monometallic diynyl radicals, [Mo(C≡C–C≡CR)L2(η-C7H7)]˙+ (L2 = bipy, R = SiMe3; L2 = dppe, R = SiMe3 or H), are reported; the (L2 = dppe, R = SiMe3) derivative is reactive to chain-centred Cβ–Cβ′ dimerisation.

AB - The unprecedented spectroscopic and structural characterisation of a series of 17-electron, monometallic diynyl radicals, [Mo(C≡C–C≡CR)L2(η-C7H7)]˙+ (L2 = bipy, R = SiMe3; L2 = dppe, R = SiMe3 or H), are reported; the (L2 = dppe, R = SiMe3) derivative is reactive to chain-centred Cβ–Cβ′ dimerisation.

U2 - 10.1039/b924759a

DO - 10.1039/b924759a

M3 - Article

C2 - 20234923

VL - 46

SP - 2253

EP - 2255

JO - Chemical Communications, 2000

JF - Chemical Communications, 2000

SN - 1359-7345

IS - 13

ER -

Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe3)L2(η-C7H7)]•+ (L2 = 2,2′-bipyridine or dppe)

Abstract

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Metal-stabilised diynyl radicals: structure and reactivity of [Mo(C≡C-C≡CSiMe₃)L₂(η-C₇H₇)]^•+(L₂ = 2,2′-bipyridine or dppe)