TY - JOUR
T1 - Metal Oxide-Impregnated Biochar for Azo Dye Remediation as Revealed through Kinetics, Thermodynamics, and Response Surface Methodology
AU - Aslam, Adeel
AU - Batool, Fozia
AU - Noreen, Sobia
AU - Abdelrahman, Ehab A.
AU - Mustaqeem, Muhammad
AU - Albalawi, Bedur Faleh A.
AU - Ditta, Allah
N1 - Funding Information:
The authors are highly thankful to the Institute of Chemistry, University of Sargodha, Pakistan, for the provision of research facilities for the present resented research work.
Publisher Copyright:
© 2024 The Authors. Published by American Chemical Society
PY - 2024/1/30
Y1 - 2024/1/30
N2 - This study reports for the first time the adsorption capacity of a novel adsorbent Croton bonplandianus Baill. biochar. Its adsorption capacity was further enhanced by loading magnetic composites on it, which makes it an efficient medium for the adsorption of dyes. Two azo dyes, Basic Brown 1 (BB1) and Basic Orange 2 (BO2), were studied for their effective adsorption from aqueous media. A comprehensive characterization was performed by using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to study the properties of Fe2O3-loaded C. bonplandianus Baill. biochar (FO-CBPBB). A series of batch experiments were conducted to optimize various parameters (pH, contact time, adsorbent amount, initial BB1 and BO2 concentrations, and temperature) for the maximum adsorption of BB1 and BO2 on the FO-CBPBB adsorbent. The percentage of BB1 and BO2 dyes that adsorb to FO-CBPBB under the best experimental circumstances (pH of solution 7, contact time 80 min, temperature of solution 40 °C, initial BB1 and BO2 dye concentrations 80 mg L-1, and adsorbent dose 1 g L-1) was 93 and 95%, respectively. The best adsorption of BB1 and BO2 was accomplished by optimizing the effects of several factors, including the starting dye concentration, contact time, and temperature, based on the central composite design. The Freundlich and Langmuir isotherm models were used to examine the equilibrium data. The Langmuir isotherm with the greatest adsorption capacity and R2 value effectively captured the experimental results. When kinetic parameters were investigated, it was found that pseudo-second-order was appropriate, reflecting the fact that the dye-adsorbent interaction was the rate-controlling factor in this study. The sorption process was endothermic and spontaneous, as shown by the thermodynamic variables. Based on the interaction between the adsorbent and azo dyes, it was concluded that the adsorption process was electrostatic in nature. Adsorbents that have been synthesized can effectively remove azo dyes from wastewater. Excellent regeneration efficiency was exhibited by FO-CBPBB, which makes it an eco-friendly and cost-effective alternative to other costly techniques applied for water purification.
AB - This study reports for the first time the adsorption capacity of a novel adsorbent Croton bonplandianus Baill. biochar. Its adsorption capacity was further enhanced by loading magnetic composites on it, which makes it an efficient medium for the adsorption of dyes. Two azo dyes, Basic Brown 1 (BB1) and Basic Orange 2 (BO2), were studied for their effective adsorption from aqueous media. A comprehensive characterization was performed by using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to study the properties of Fe2O3-loaded C. bonplandianus Baill. biochar (FO-CBPBB). A series of batch experiments were conducted to optimize various parameters (pH, contact time, adsorbent amount, initial BB1 and BO2 concentrations, and temperature) for the maximum adsorption of BB1 and BO2 on the FO-CBPBB adsorbent. The percentage of BB1 and BO2 dyes that adsorb to FO-CBPBB under the best experimental circumstances (pH of solution 7, contact time 80 min, temperature of solution 40 °C, initial BB1 and BO2 dye concentrations 80 mg L-1, and adsorbent dose 1 g L-1) was 93 and 95%, respectively. The best adsorption of BB1 and BO2 was accomplished by optimizing the effects of several factors, including the starting dye concentration, contact time, and temperature, based on the central composite design. The Freundlich and Langmuir isotherm models were used to examine the equilibrium data. The Langmuir isotherm with the greatest adsorption capacity and R2 value effectively captured the experimental results. When kinetic parameters were investigated, it was found that pseudo-second-order was appropriate, reflecting the fact that the dye-adsorbent interaction was the rate-controlling factor in this study. The sorption process was endothermic and spontaneous, as shown by the thermodynamic variables. Based on the interaction between the adsorbent and azo dyes, it was concluded that the adsorption process was electrostatic in nature. Adsorbents that have been synthesized can effectively remove azo dyes from wastewater. Excellent regeneration efficiency was exhibited by FO-CBPBB, which makes it an eco-friendly and cost-effective alternative to other costly techniques applied for water purification.
UR - http://www.scopus.com/inward/record.url?scp=85183015202&partnerID=8YFLogxK
U2 - 10.1021/acsomega.3c05321
DO - 10.1021/acsomega.3c05321
M3 - Article
C2 - 38313481
AN - SCOPUS:85183015202
SN - 2470-1343
VL - 9
SP - 4300
EP - 4316
JO - ACS Omega
JF - ACS Omega
IS - 4
ER -