Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid

V.J. Hesler; Brian Skelton; Allan White; David Brown; Murray Baker

doi:10.1007/s10847-015-0522-y

Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid

V.J. Hesler, Brian Skelton, Allan White, David Brown, Murray Baker

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Abstract

© Springer Science+Business Media Dordrecht 2015. Reaction of mercuric acetate with an imidazolium-linked cyclophane incorporating 2,6-phenolic moieties results in formation of an interesting new N-heterocyclic carbene (NHC) complex of mercury. The new complex is cationic and binuclear, incorporating two mercury centres and two bis(NHC) ligands, each mercury atom being bound by two NHC moieties and two phenol/phenoxy moieties. Forms of the complex having coordinating ((Formula presented.))and non-coordinating ((Formula presented.))counterions have been structurally characterised.

Original language	English
Pages (from-to)	71-78
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	82
Issue number	1-2
Early online date	3 May 2015
DOIs	https://doi.org/10.1007/s10847-015-0522-y
Publication status	Published - Jun 2015

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title = "Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid",

abstract = "{\textcopyright} Springer Science+Business Media Dordrecht 2015. Reaction of mercuric acetate with an imidazolium-linked cyclophane incorporating 2,6-phenolic moieties results in formation of an interesting new N-heterocyclic carbene (NHC) complex of mercury. The new complex is cationic and binuclear, incorporating two mercury centres and two bis(NHC) ligands, each mercury atom being bound by two NHC moieties and two phenol/phenoxy moieties. Forms of the complex having coordinating ((Formula presented.))and non-coordinating ((Formula presented.))counterions have been structurally characterised.",

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AU - Hesler, V.J.

AU - Skelton, Brian

AU - White, Allan

AU - Brown, David

AU - Baker, Murray

PY - 2015/6

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N2 - © Springer Science+Business Media Dordrecht 2015. Reaction of mercuric acetate with an imidazolium-linked cyclophane incorporating 2,6-phenolic moieties results in formation of an interesting new N-heterocyclic carbene (NHC) complex of mercury. The new complex is cationic and binuclear, incorporating two mercury centres and two bis(NHC) ligands, each mercury atom being bound by two NHC moieties and two phenol/phenoxy moieties. Forms of the complex having coordinating ((Formula presented.))and non-coordinating ((Formula presented.))counterions have been structurally characterised.

AB - © Springer Science+Business Media Dordrecht 2015. Reaction of mercuric acetate with an imidazolium-linked cyclophane incorporating 2,6-phenolic moieties results in formation of an interesting new N-heterocyclic carbene (NHC) complex of mercury. The new complex is cationic and binuclear, incorporating two mercury centres and two bis(NHC) ligands, each mercury atom being bound by two NHC moieties and two phenol/phenoxy moieties. Forms of the complex having coordinating ((Formula presented.))and non-coordinating ((Formula presented.))counterions have been structurally characterised.

UR - https://www.scopus.com/pages/publications/84944071304

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JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

IS - 1-2

ER -

Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid

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Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural and Mechanistic Approach

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Mercury complexes of an N-heterocyclic carbene derived from a calixarene/azolium cyclophane hybrid

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Cyclophane Carbene Complexes as Catalysts: An Integrated Synthetic, Structural and Mechanistic Approach

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