Magneto-electronic properties and structural features of unusual bis(mu-aqua) bis(mu-sulfato) bridges in binuclear cobalt-based 4-aminopyridine

Nabil Hfidhi, Marcus Korb, Magdalena Fitta, Erik Cizmar, Heinrich Lang, Houcine Naili

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In order to improve the relationship between the structure of bridging dinuclear complexes and their magnetic behavior, we did synthesize metal-organic [Co-2(mu(2)-H2O)(2)(mu(2)-SO4)(2)(C5H6N2)(4)]center dot 2.86(C2H6OS)center dot 2.88(C4H8O) 1. This dinuclear transition metal complex was characterized by infrared and UV-vis spectroscopy as well as single X-ray diffraction. The thermal and magnetic behavior of this complex was studied. Single crystal X-ray diffraction studies confirmed that 1 consists of discrete dinuclear cobalt entities and two free solvent molecules (DMSO, THF). The two cobalt ions are bridged by two water oxygen atoms and two bidentate sulfate groups to form a four bridged dinuclear core. The optical band gap was determined by diffuse reflection spectroscopy to 3.06 eV for an indirect forbidden transition. The magnetic measurements and DFT calculations suggest the presence of ferromagnetic exchange between Co(II) centers with a strong easy-axis anisotropy.

Original languageEnglish
Pages (from-to)206-213
Number of pages8
JournalInorganica Chimica Acta
Volume484
DOIs
Publication statusPublished - 1 Jan 2019
Externally publishedYes

Cite this

Hfidhi, Nabil ; Korb, Marcus ; Fitta, Magdalena ; Cizmar, Erik ; Lang, Heinrich ; Naili, Houcine. / Magneto-electronic properties and structural features of unusual bis(mu-aqua) bis(mu-sulfato) bridges in binuclear cobalt-based 4-aminopyridine. In: Inorganica Chimica Acta. 2019 ; Vol. 484. pp. 206-213.
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abstract = "In order to improve the relationship between the structure of bridging dinuclear complexes and their magnetic behavior, we did synthesize metal-organic [Co-2(mu(2)-H2O)(2)(mu(2)-SO4)(2)(C5H6N2)(4)]center dot 2.86(C2H6OS)center dot 2.88(C4H8O) 1. This dinuclear transition metal complex was characterized by infrared and UV-vis spectroscopy as well as single X-ray diffraction. The thermal and magnetic behavior of this complex was studied. Single crystal X-ray diffraction studies confirmed that 1 consists of discrete dinuclear cobalt entities and two free solvent molecules (DMSO, THF). The two cobalt ions are bridged by two water oxygen atoms and two bidentate sulfate groups to form a four bridged dinuclear core. The optical band gap was determined by diffuse reflection spectroscopy to 3.06 eV for an indirect forbidden transition. The magnetic measurements and DFT calculations suggest the presence of ferromagnetic exchange between Co(II) centers with a strong easy-axis anisotropy.",
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author = "Nabil Hfidhi and Marcus Korb and Magdalena Fitta and Erik Cizmar and Heinrich Lang and Houcine Naili",
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Magneto-electronic properties and structural features of unusual bis(mu-aqua) bis(mu-sulfato) bridges in binuclear cobalt-based 4-aminopyridine. / Hfidhi, Nabil; Korb, Marcus; Fitta, Magdalena; Cizmar, Erik; Lang, Heinrich; Naili, Houcine.

In: Inorganica Chimica Acta, Vol. 484, 01.01.2019, p. 206-213.

Research output: Contribution to journalArticle

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T1 - Magneto-electronic properties and structural features of unusual bis(mu-aqua) bis(mu-sulfato) bridges in binuclear cobalt-based 4-aminopyridine

AU - Hfidhi, Nabil

AU - Korb, Marcus

AU - Fitta, Magdalena

AU - Cizmar, Erik

AU - Lang, Heinrich

AU - Naili, Houcine

PY - 2019/1/1

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N2 - In order to improve the relationship between the structure of bridging dinuclear complexes and their magnetic behavior, we did synthesize metal-organic [Co-2(mu(2)-H2O)(2)(mu(2)-SO4)(2)(C5H6N2)(4)]center dot 2.86(C2H6OS)center dot 2.88(C4H8O) 1. This dinuclear transition metal complex was characterized by infrared and UV-vis spectroscopy as well as single X-ray diffraction. The thermal and magnetic behavior of this complex was studied. Single crystal X-ray diffraction studies confirmed that 1 consists of discrete dinuclear cobalt entities and two free solvent molecules (DMSO, THF). The two cobalt ions are bridged by two water oxygen atoms and two bidentate sulfate groups to form a four bridged dinuclear core. The optical band gap was determined by diffuse reflection spectroscopy to 3.06 eV for an indirect forbidden transition. The magnetic measurements and DFT calculations suggest the presence of ferromagnetic exchange between Co(II) centers with a strong easy-axis anisotropy.

AB - In order to improve the relationship between the structure of bridging dinuclear complexes and their magnetic behavior, we did synthesize metal-organic [Co-2(mu(2)-H2O)(2)(mu(2)-SO4)(2)(C5H6N2)(4)]center dot 2.86(C2H6OS)center dot 2.88(C4H8O) 1. This dinuclear transition metal complex was characterized by infrared and UV-vis spectroscopy as well as single X-ray diffraction. The thermal and magnetic behavior of this complex was studied. Single crystal X-ray diffraction studies confirmed that 1 consists of discrete dinuclear cobalt entities and two free solvent molecules (DMSO, THF). The two cobalt ions are bridged by two water oxygen atoms and two bidentate sulfate groups to form a four bridged dinuclear core. The optical band gap was determined by diffuse reflection spectroscopy to 3.06 eV for an indirect forbidden transition. The magnetic measurements and DFT calculations suggest the presence of ferromagnetic exchange between Co(II) centers with a strong easy-axis anisotropy.

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KW - STATE PERTURBATION-THEORY

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

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KW - FORMULATION

KW - EXCHANGE

KW - LIGANDS

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KW - 1D

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