Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene

Becky Fuller, K.L. Livesey, Rob Woodward, Allan Mckinley, Brian Skelton, George Koutsantonis

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

© CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.
Original languageEnglish
Pages (from-to)1588-1594
JournalAustralian Journal of Chemistry
Volume67
Issue number11
DOIs
Publication statusPublished - 2014

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