Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene

Becky Fuller, K.L. Livesey, Rob Woodward, Allan Mckinley, Brian Skelton, George Koutsantonis

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

© CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.
Original languageEnglish
Pages (from-to)1588-1594
JournalAustralian Journal of Chemistry
Volume67
Issue number11
DOIs
Publication statusPublished - 2014

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Metal ions
Jahn-Teller effect
Exchange coupling
Excited states
Ground state
Temperature
thiacalix(4)arene
Hot Temperature

Cite this

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title = "Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene",
abstract = "{\circledC} CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.",
author = "Becky Fuller and K.L. Livesey and Rob Woodward and Allan Mckinley and Brian Skelton and George Koutsantonis",
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Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene. / Fuller, Becky; Livesey, K.L.; Woodward, Rob; Mckinley, Allan; Skelton, Brian; Koutsantonis, George.

In: Australian Journal of Chemistry, Vol. 67, No. 11, 2014, p. 1588-1594.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene

AU - Fuller, Becky

AU - Livesey, K.L.

AU - Woodward, Rob

AU - Mckinley, Allan

AU - Skelton, Brian

AU - Koutsantonis, George

PY - 2014

Y1 - 2014

N2 - © CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.

AB - © CSIRO 2014. Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn-Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.

U2 - 10.1071/CH14136

DO - 10.1071/CH14136

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VL - 67

SP - 1588

EP - 1594

JO - Australian Journal of Chemistry:an international journal for chemical science

JF - Australian Journal of Chemistry:an international journal for chemical science

SN - 0004-9425

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