Magnetic properties of calixarene-supported metal coordination clusters

Rebecca O. Fuller, George A. Koutsantonis, Mark I. Ogden

Research output: Contribution to journalReview article

Abstract

Multinuclear metal complexes have shown a unique capacity to provide interesting magnetic, chemical and electronic properties by virtue of the remarkably diverse range of structural types that they exhibit. Calix[n]arenes are now a mature synthetic platfom that provide for a diverse spatial arrangement of binding groups, making them highly suitable to use for the formation of multinuclear metal ion complexes. Increasing interest has been shown in the development and properties of magnetic materials based on calixarene macrocycles. Here, we review the magnetic properties of calixarene-supported metal clusters with emphasis on those examples exhibiting slow magnetic relaxation. (C) 2019 Elsevier B.V. All rights reserved.

Original languageEnglish
Article number213066
Number of pages17
JournalCoordination Chemistry Reviews
Volume402
DOIs
Publication statusPublished - 1 Jan 2020

Cite this

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title = "Magnetic properties of calixarene-supported metal coordination clusters",
abstract = "Multinuclear metal complexes have shown a unique capacity to provide interesting magnetic, chemical and electronic properties by virtue of the remarkably diverse range of structural types that they exhibit. Calix[n]arenes are now a mature synthetic platfom that provide for a diverse spatial arrangement of binding groups, making them highly suitable to use for the formation of multinuclear metal ion complexes. Increasing interest has been shown in the development and properties of magnetic materials based on calixarene macrocycles. Here, we review the magnetic properties of calixarene-supported metal clusters with emphasis on those examples exhibiting slow magnetic relaxation. (C) 2019 Elsevier B.V. All rights reserved.",
keywords = "Calixarenes, Magnetism, Supramolecular chemistry, Cluster compounds, SINGLE-MOLECULE MAGNETS, TETRANUCLEAR MANGANESE(II) COMPLEXES, TRANSITION-METAL, THIACALIXARENE MACROCYCLES, 2ND-SPHERE COORDINATION, BUILDING-BLOCKS, LIGANDS, LN, 3D-4F, CHEMISTRY",
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language = "English",
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journal = "Coordination Chemistry Reviews",
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Magnetic properties of calixarene-supported metal coordination clusters. / Fuller, Rebecca O.; Koutsantonis, George A.; Ogden, Mark I.

In: Coordination Chemistry Reviews, Vol. 402, 213066, 01.01.2020.

Research output: Contribution to journalReview article

TY - JOUR

T1 - Magnetic properties of calixarene-supported metal coordination clusters

AU - Fuller, Rebecca O.

AU - Koutsantonis, George A.

AU - Ogden, Mark I.

PY - 2020/1/1

Y1 - 2020/1/1

N2 - Multinuclear metal complexes have shown a unique capacity to provide interesting magnetic, chemical and electronic properties by virtue of the remarkably diverse range of structural types that they exhibit. Calix[n]arenes are now a mature synthetic platfom that provide for a diverse spatial arrangement of binding groups, making them highly suitable to use for the formation of multinuclear metal ion complexes. Increasing interest has been shown in the development and properties of magnetic materials based on calixarene macrocycles. Here, we review the magnetic properties of calixarene-supported metal clusters with emphasis on those examples exhibiting slow magnetic relaxation. (C) 2019 Elsevier B.V. All rights reserved.

AB - Multinuclear metal complexes have shown a unique capacity to provide interesting magnetic, chemical and electronic properties by virtue of the remarkably diverse range of structural types that they exhibit. Calix[n]arenes are now a mature synthetic platfom that provide for a diverse spatial arrangement of binding groups, making them highly suitable to use for the formation of multinuclear metal ion complexes. Increasing interest has been shown in the development and properties of magnetic materials based on calixarene macrocycles. Here, we review the magnetic properties of calixarene-supported metal clusters with emphasis on those examples exhibiting slow magnetic relaxation. (C) 2019 Elsevier B.V. All rights reserved.

KW - Calixarenes

KW - Magnetism

KW - Supramolecular chemistry

KW - Cluster compounds

KW - SINGLE-MOLECULE MAGNETS

KW - TETRANUCLEAR MANGANESE(II) COMPLEXES

KW - TRANSITION-METAL

KW - THIACALIXARENE MACROCYCLES

KW - 2ND-SPHERE COORDINATION

KW - BUILDING-BLOCKS

KW - LIGANDS

KW - LN

KW - 3D-4F

KW - CHEMISTRY

U2 - 10.1016/j.ccr.2019.213066

DO - 10.1016/j.ccr.2019.213066

M3 - Review article

VL - 402

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

M1 - 213066

ER -