TY - JOUR
T1 - Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXXV Structural Systematics of the Binuclear Copper(I) Halide: 1,5-Cyclooctadiene (‘cod’) 2:2 Adducts, [(cod)Cu(μ-X)2Cu(cod)], X = Cl, Br, I
AU - Kok, J.M.
AU - Skelton, Brian
AU - White, Allan
PY - 2004
Y1 - 2004
N2 - Adducts of 1,5-cyclooctadiene (lsquocodrsquo) with the copper(I) halides, CuX (X = Cl, Br, I) of 1:1 stoichiometry are confirmed as binuclear species of [(cod)Cu(mgr-X)2Cu(cod)] by single crystal X-ray studies, those for X = Cl, I being executed at low-temperature. The study for X = Cl is a redetermination, exposing disorder in one of the copper atom sites; a similar redetermination of [Cu(cod)2](ClO4) shows disorder in respect of one of the ligands. Bonding parameters are compared with those for other Lewis-base analogues.
AB - Adducts of 1,5-cyclooctadiene (lsquocodrsquo) with the copper(I) halides, CuX (X = Cl, Br, I) of 1:1 stoichiometry are confirmed as binuclear species of [(cod)Cu(mgr-X)2Cu(cod)] by single crystal X-ray studies, those for X = Cl, I being executed at low-temperature. The study for X = Cl is a redetermination, exposing disorder in one of the copper atom sites; a similar redetermination of [Cu(cod)2](ClO4) shows disorder in respect of one of the ligands. Bonding parameters are compared with those for other Lewis-base analogues.
U2 - 10.1023/B:JOCL.0000041200.84420.45
DO - 10.1023/B:JOCL.0000041200.84420.45
M3 - Article
SN - 1040-7278
VL - 15
SP - 365
EP - 376
JO - Journal of Cluster Science
JF - Journal of Cluster Science
IS - 3
ER -