"Lattice Strain Matching"-Enabled Nanocomposite Design to Harness the Exceptional Mechanical Properties of Nanomaterials in Bulk Forms

Junsong Zhang, Yinong Liu, Lishan Cui, Shijie Hao, Daqiang Jiang, Kaiyuan Yu, Shengcheng Mao, Yang Ren, Hong Yang

Research output: Contribution to journalArticle

Abstract

Nanosized materials are known to have the ability to withstand ultralarge elastic strains (4-10%) and to have ultrahigh strengths approaching their theoretical limits. However, it is a long-standing challenge to harnessing their exceptional intrinsic mechanical properties in bulk forms. This is commonly known as "the valley of death" in nanocomposite design. In 2013, a breakthrough was made to overcome this challenge by using a martensitic phase transforming matrix to create a composite in which ultralarge elastic lattice strains up to 6.7% are achieved in Nb nanoribbons embedded in it. This breakthrough was enabled by a novel concept of phase transformation assisted lattice strain matching between the uniform ultralarge elastic strains (4-10%) of nanomaterials and the uniform crystallographic lattice distortion strains (4-10%) of the martensitic phase transformation of the matrix. This novel concept has opened new opportunities for developing materials of exceptional mechanical properties or enhanced functional properties that are not possible before. The work in progress in this research over the past six years is reported.

Original languageEnglish
Article number1904387
Number of pages11
JournalAdvanced Materials
DOIs
Publication statusE-pub ahead of print - 19 Sep 2019

Cite this

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title = "{"}Lattice Strain Matching{"}-Enabled Nanocomposite Design to Harness the Exceptional Mechanical Properties of Nanomaterials in Bulk Forms",
abstract = "Nanosized materials are known to have the ability to withstand ultralarge elastic strains (4-10{\%}) and to have ultrahigh strengths approaching their theoretical limits. However, it is a long-standing challenge to harnessing their exceptional intrinsic mechanical properties in bulk forms. This is commonly known as {"}the valley of death{"} in nanocomposite design. In 2013, a breakthrough was made to overcome this challenge by using a martensitic phase transforming matrix to create a composite in which ultralarge elastic lattice strains up to 6.7{\%} are achieved in Nb nanoribbons embedded in it. This breakthrough was enabled by a novel concept of phase transformation assisted lattice strain matching between the uniform ultralarge elastic strains (4-10{\%}) of nanomaterials and the uniform crystallographic lattice distortion strains (4-10{\%}) of the martensitic phase transformation of the matrix. This novel concept has opened new opportunities for developing materials of exceptional mechanical properties or enhanced functional properties that are not possible before. The work in progress in this research over the past six years is reported.",
keywords = "elastic strain, martensitic transformation, nanocomposites, shape-memory alloys, ELASTIC STRAIN, DEFORMATION-BEHAVIOR, STRENGTH, ULTRALARGE, LIMIT",
author = "Junsong Zhang and Yinong Liu and Lishan Cui and Shijie Hao and Daqiang Jiang and Kaiyuan Yu and Shengcheng Mao and Yang Ren and Hong Yang",
year = "2019",
month = "9",
day = "19",
doi = "10.1002/adma.201904387",
language = "English",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",

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"Lattice Strain Matching"-Enabled Nanocomposite Design to Harness the Exceptional Mechanical Properties of Nanomaterials in Bulk Forms. / Zhang, Junsong; Liu, Yinong; Cui, Lishan; Hao, Shijie; Jiang, Daqiang; Yu, Kaiyuan; Mao, Shengcheng; Ren, Yang; Yang, Hong.

In: Advanced Materials, 19.09.2019.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Zhang, Junsong

AU - Liu, Yinong

AU - Cui, Lishan

AU - Hao, Shijie

AU - Jiang, Daqiang

AU - Yu, Kaiyuan

AU - Mao, Shengcheng

AU - Ren, Yang

AU - Yang, Hong

PY - 2019/9/19

Y1 - 2019/9/19

N2 - Nanosized materials are known to have the ability to withstand ultralarge elastic strains (4-10%) and to have ultrahigh strengths approaching their theoretical limits. However, it is a long-standing challenge to harnessing their exceptional intrinsic mechanical properties in bulk forms. This is commonly known as "the valley of death" in nanocomposite design. In 2013, a breakthrough was made to overcome this challenge by using a martensitic phase transforming matrix to create a composite in which ultralarge elastic lattice strains up to 6.7% are achieved in Nb nanoribbons embedded in it. This breakthrough was enabled by a novel concept of phase transformation assisted lattice strain matching between the uniform ultralarge elastic strains (4-10%) of nanomaterials and the uniform crystallographic lattice distortion strains (4-10%) of the martensitic phase transformation of the matrix. This novel concept has opened new opportunities for developing materials of exceptional mechanical properties or enhanced functional properties that are not possible before. The work in progress in this research over the past six years is reported.

AB - Nanosized materials are known to have the ability to withstand ultralarge elastic strains (4-10%) and to have ultrahigh strengths approaching their theoretical limits. However, it is a long-standing challenge to harnessing their exceptional intrinsic mechanical properties in bulk forms. This is commonly known as "the valley of death" in nanocomposite design. In 2013, a breakthrough was made to overcome this challenge by using a martensitic phase transforming matrix to create a composite in which ultralarge elastic lattice strains up to 6.7% are achieved in Nb nanoribbons embedded in it. This breakthrough was enabled by a novel concept of phase transformation assisted lattice strain matching between the uniform ultralarge elastic strains (4-10%) of nanomaterials and the uniform crystallographic lattice distortion strains (4-10%) of the martensitic phase transformation of the matrix. This novel concept has opened new opportunities for developing materials of exceptional mechanical properties or enhanced functional properties that are not possible before. The work in progress in this research over the past six years is reported.

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KW - STRENGTH

KW - ULTRALARGE

KW - LIMIT

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