Lanthanide(III) solvation: N,N'-dimethylformamide as a unidentate O-donor

J.M. Harrowfield; Brian Skelton; Allan White; F. Wilner

doi:10.1016/j.ica.2004.01.008

Lanthanide(III) solvation: N,N'-dimethylformamide as a unidentate O-donor

J.M. Harrowfield, Brian Skelton, Allan White, F. Wilner

Research output: Contribution to journal › Article

41 Citations (Scopus)

Abstract

Structure determinations for the lanthanide (Ln) complexes [(CH3)(2)NH2][Gd(dmf)(8)](ClO4)(4), [Tb(dmf)(8)](ClO4)(3) and [Ho(dMf)(7)(OH2)](ClO4)(3) (dmf=N,N-dimethylformamide) show all three to contain an LnO(8) coordination unit of essentially square-antiprismatic geometry. The geometry of the inner coordination sphere appears to be little perturbed by quite major differences in the lattice environment of the cations. Attractive interactions between coordinated dmf molecules may be one contributor to the stability of the primary coordination sphere. (C) 2004 Published by Elsevier B.V.

Original language	English
Pages (from-to)	2358-2364
Journal	Inorganica Chimica Acta
Volume	357
Issue number	8
DOIs	https://doi.org/10.1016/j.ica.2004.01.008
Publication status	Published - 2004

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@article{264ae06589894068a697e83dd5530d61,

title = "Lanthanide(III) solvation: N,N'-dimethylformamide as a unidentate O-donor",

abstract = "Structure determinations for the lanthanide (Ln) complexes [(CH3)(2)NH2][Gd(dmf)(8)](ClO4)(4), [Tb(dmf)(8)](ClO4)(3) and [Ho(dMf)(7)(OH2)](ClO4)(3) (dmf=N,N-dimethylformamide) show all three to contain an LnO(8) coordination unit of essentially square-antiprismatic geometry. The geometry of the inner coordination sphere appears to be little perturbed by quite major differences in the lattice environment of the cations. Attractive interactions between coordinated dmf molecules may be one contributor to the stability of the primary coordination sphere. (C) 2004 Published by Elsevier B.V.",

author = "J.M. Harrowfield and Brian Skelton and Allan White and F. Wilner",

year = "2004",

doi = "10.1016/j.ica.2004.01.008",

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pages = "2358--2364",

journal = "Inorganica Chemica Acta",

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publisher = "Elsevier Science & Technology",

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TY - JOUR

T1 - Lanthanide(III) solvation: N,N'-dimethylformamide as a unidentate O-donor

AU - Harrowfield, J.M.

AU - Skelton, Brian

AU - White, Allan

AU - Wilner, F.

PY - 2004

Y1 - 2004

N2 - Structure determinations for the lanthanide (Ln) complexes [(CH3)(2)NH2][Gd(dmf)(8)](ClO4)(4), [Tb(dmf)(8)](ClO4)(3) and [Ho(dMf)(7)(OH2)](ClO4)(3) (dmf=N,N-dimethylformamide) show all three to contain an LnO(8) coordination unit of essentially square-antiprismatic geometry. The geometry of the inner coordination sphere appears to be little perturbed by quite major differences in the lattice environment of the cations. Attractive interactions between coordinated dmf molecules may be one contributor to the stability of the primary coordination sphere. (C) 2004 Published by Elsevier B.V.

AB - Structure determinations for the lanthanide (Ln) complexes [(CH3)(2)NH2][Gd(dmf)(8)](ClO4)(4), [Tb(dmf)(8)](ClO4)(3) and [Ho(dMf)(7)(OH2)](ClO4)(3) (dmf=N,N-dimethylformamide) show all three to contain an LnO(8) coordination unit of essentially square-antiprismatic geometry. The geometry of the inner coordination sphere appears to be little perturbed by quite major differences in the lattice environment of the cations. Attractive interactions between coordinated dmf molecules may be one contributor to the stability of the primary coordination sphere. (C) 2004 Published by Elsevier B.V.

U2 - 10.1016/j.ica.2004.01.008

DO - 10.1016/j.ica.2004.01.008

M3 - Article

VL - 357

SP - 2358

EP - 2364

JO - Inorganica Chemica Acta

JF - Inorganica Chemica Acta

SN - 0020-1693

IS - 8

ER -