TY - JOUR
T1 - Lanthanide(II) and -(III) Porphyrinogens - Rational Synthesis and Derivatisation of Mononuclear, Alkali-Metal-Free Lanthanide(II) and -(III) meso-Octaalkylporphyrinogen Complexes
AU - Wang, J.
AU - Dick, A.K.J.
AU - Gardiner, M.G.
AU - Yates, B.F.
AU - Peacock, E.J.
AU - Skelton, Brian
AU - White, Allan
PY - 2004
Y1 - 2004
N2 - Modifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N'-dimethylation results in Sm-II and Sm-III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm-II bis(tetrahydrofuran) adduct, Sm-III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, H-1 and C-13 NMR spectroscopy and X-ray crystal structure determinations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
AB - Modifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N'-dimethylation results in Sm-II and Sm-III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm-II bis(tetrahydrofuran) adduct, Sm-III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, H-1 and C-13 NMR spectroscopy and X-ray crystal structure determinations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
U2 - 10.1002/ejic.200300965
DO - 10.1002/ejic.200300965
M3 - Article
SN - 1434-1948
VL - 2004
SP - 1992
EP - 1995
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
ER -