© 2015, Nature Publishing Group. All rights reserved. We investigate, for the first time, navigation on networks with a Lévy walk strategy such that the step probability scales as pij∼dij -α, where dij is the Manhattan distance between nodes i and j, and α is the transport exponent. We find that the optimal transport exponent αopt of such a diffusion process is determined by the fractal dimension df of the underlying network. Specially, we theoretically derive the relation αopt=df+2 for synthetic networks and we demonstrate that this holds for a number of real-world networks. Interestingly, the relationship we derive is different from previous results for Kleinberg navigation without or with a cost constraint, where the optimal conditions are α = df and α = df + 1, respectively. Our results uncover another general mechanism for how network dimension can precisely govern the efficient diffusion behavior on diverse networks.