Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes

M.I. Bruce; M. Jevric; C.R. Parker; W. Patalinghug; Brian Skelton; Allan White; N.N. Zaitseva

doi:10.1016/j.jorganchem.2008.06.008

Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes

M.I. Bruce
, M. Jevric
, C.R. Parker
, W. Patalinghug
, Brian Skelton
, Allan White
, N.N. Zaitseva

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Addition of [ I( py) 2] BF4 to Ru( C, CH)( dppe) Cp* gave the iodovinylidene [ Ru(@ C@ CHI)( dppe) Cp*] BF4 1, which could be deprotonated to Ru( C, CI)( dppe) Cp* 2. The attempted preparation of Ru( C, C C, CI)( dppe) Cp*, followed by derivatisation with tcne, gave the dienynyl Ru{C, CC[@ C( CN) 2]CI@ C( CN) 2}( dppe) Cp* 3. The Pd( 0)/ Cu( I)- catalysed reaction of 3 with Ru{C, CC, CAu( PPh3)}( dppe) Cp* afforded Ru{C, CC@ C( CN) 2C@ C( CN) 2Au( PPh3)}( dppe) Cp* 4 by formal replacement of I+ by [ Au( PPh3)]+. XRD structures of 1 - 4 are reported. (c) 2008 Elsevier B. V. All rights reserved.

Original language	English
Pages (from-to)	2915-2950
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	17
DOIs	https://doi.org/10.1016/j.jorganchem.2008.06.008
Publication status	Published - 2008

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10.1016/j.jorganchem.2008.06.008

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title = "Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes",

abstract = "Addition of [ I( py) 2] BF4 to Ru( C, CH)( dppe) Cp* gave the iodovinylidene [ Ru(@ C@ CHI)( dppe) Cp*] BF4 1, which could be deprotonated to Ru( C, CI)( dppe) Cp* 2. The attempted preparation of Ru( C, C C, CI)( dppe) Cp*, followed by derivatisation with tcne, gave the dienynyl Ru\{C, CC[@ C( CN) 2]CI@ C( CN) 2\}( dppe) Cp* 3. The Pd( 0)/ Cu( I)- catalysed reaction of 3 with Ru\{C, CC, CAu( PPh3)\}( dppe) Cp* afforded Ru\{C, CC@ C( CN) 2C@ C( CN) 2Au( PPh3)\}( dppe) Cp* 4 by formal replacement of I+ by [ Au( PPh3)]+. XRD structures of 1 - 4 are reported. (c) 2008 Elsevier B. V. All rights reserved.",

author = "M.I. Bruce and M. Jevric and C.R. Parker and W. Patalinghug and Brian Skelton and Allan White and N.N. Zaitseva",

year = "2008",

doi = "10.1016/j.jorganchem.2008.06.008",

language = "English",

volume = "693",

pages = "2915--2950",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

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}

TY - JOUR

T1 - Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes

AU - Bruce, M.I.

AU - Jevric, M.

AU - Parker, C.R.

AU - Patalinghug, W.

AU - Skelton, Brian

AU - White, Allan

AU - Zaitseva, N.N.

PY - 2008

Y1 - 2008

N2 - Addition of [ I( py) 2] BF4 to Ru( C, CH)( dppe) Cp* gave the iodovinylidene [ Ru(@ C@ CHI)( dppe) Cp*] BF4 1, which could be deprotonated to Ru( C, CI)( dppe) Cp* 2. The attempted preparation of Ru( C, C C, CI)( dppe) Cp*, followed by derivatisation with tcne, gave the dienynyl Ru{C, CC[@ C( CN) 2]CI@ C( CN) 2}( dppe) Cp* 3. The Pd( 0)/ Cu( I)- catalysed reaction of 3 with Ru{C, CC, CAu( PPh3)}( dppe) Cp* afforded Ru{C, CC@ C( CN) 2C@ C( CN) 2Au( PPh3)}( dppe) Cp* 4 by formal replacement of I+ by [ Au( PPh3)]+. XRD structures of 1 - 4 are reported. (c) 2008 Elsevier B. V. All rights reserved.

AB - Addition of [ I( py) 2] BF4 to Ru( C, CH)( dppe) Cp* gave the iodovinylidene [ Ru(@ C@ CHI)( dppe) Cp*] BF4 1, which could be deprotonated to Ru( C, CI)( dppe) Cp* 2. The attempted preparation of Ru( C, C C, CI)( dppe) Cp*, followed by derivatisation with tcne, gave the dienynyl Ru{C, CC[@ C( CN) 2]CI@ C( CN) 2}( dppe) Cp* 3. The Pd( 0)/ Cu( I)- catalysed reaction of 3 with Ru{C, CC, CAu( PPh3)}( dppe) Cp* afforded Ru{C, CC@ C( CN) 2C@ C( CN) 2Au( PPh3)}( dppe) Cp* 4 by formal replacement of I+ by [ Au( PPh3)]+. XRD structures of 1 - 4 are reported. (c) 2008 Elsevier B. V. All rights reserved.

U2 - 10.1016/j.jorganchem.2008.06.008

DO - 10.1016/j.jorganchem.2008.06.008

M3 - Article

SN - 0022-328X

VL - 693

SP - 2915

EP - 2950

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 17

ER -

Iodo-alkynyl- and iodo-butadiynyl-ruthenium complexes

Abstract

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