Intramolecular Hydroamination of 1,4,7-Tri(pent-4' -yn-1' -yl)-1.4.7-triazacyclononane: Formation of an Azoniaspiro [4.8] tridecane

Murray Baker, David Brown, Brian Skelton, Allan White

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4 Citations (Scopus)

Abstract

In methanol solution, 1,4,7-tri(pent-4'-yn-1'-yl)-1,4,7-triazacyclononane undergoes an intramolecular hydroamination reaction to form an azoniaspiro[4.8]tridecane cation, 1-methylidene-8,11-di(pent-4'-yn-1'-yl)-8,11-diaza-5-azoniaspiro[4.8] tridecane. The azoniaspiro[4.8]tridecane cation, as its tetraphenylborate salt, has been characterized spectroscopically in solution and by X-ray studies in the solid state. Reactions of the azoniaspiro[4.8]tridecane that lead to other products are also discussed.
Original languageEnglish
Pages (from-to)791-797
JournalAustralian Journal of Chemistry
Volume53
Issue number2000
DOIs
Publication statusPublished - 2000

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