Intramolecular Heck Reactions for the Synthesis of the Novel Antibiotic Mensacarcin: Investigation of Catalytic, Electronic and Conjugative Effects in the Preparation of the Hexahydroanthracene Core

L.F. Tietze, Scott Stewart, Marta Polomska

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12 Citations (Scopus)

Abstract

The intramolecular Heck reaction of the three complex diphenylsubstrates rac-2, 5 and rac-6, containing substituentswith different electronic and conjugative properties, were examined.The Pd compounds [Pd2(dba)3]/[(tBu)3PH]BF4, [Pd2(OAc)2{P(o-Tol)3}2] (4), [PdCl2(PPh3)2] and Pd(OAc)2were used as catalysts.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,Germany, 2005)
Original languageEnglish
Pages (from-to)1752-1759
JournalEuropean Journal of Organic Chemistry
Volume2005
Issue number9
DOIs
Publication statusPublished - 2005

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