TY - JOUR
T1 - Intramolecular Heck Reactions for the Synthesis of the Novel Antibiotic Mensacarcin: Investigation of Catalytic, Electronic and Conjugative Effects in the Preparation of the Hexahydroanthracene Core
AU - Tietze, L.F.
AU - Stewart, Scott
AU - Polomska, Marta
PY - 2005
Y1 - 2005
N2 - The intramolecular Heck reaction of the three complex diphenylsubstrates rac-2, 5 and rac-6, containing substituentswith different electronic and conjugative properties, were examined.The Pd compounds [Pd2(dba)3]/[(tBu)3PH]BF4, [Pd2(OAc)2{P(o-Tol)3}2] (4), [PdCl2(PPh3)2] and Pd(OAc)2were used as catalysts.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,Germany, 2005)
AB - The intramolecular Heck reaction of the three complex diphenylsubstrates rac-2, 5 and rac-6, containing substituentswith different electronic and conjugative properties, were examined.The Pd compounds [Pd2(dba)3]/[(tBu)3PH]BF4, [Pd2(OAc)2{P(o-Tol)3}2] (4), [PdCl2(PPh3)2] and Pd(OAc)2were used as catalysts.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim,Germany, 2005)
U2 - 10.1002/ejoc.200400786
DO - 10.1002/ejoc.200400786
M3 - Article
VL - 2005
SP - 1752
EP - 1759
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1099-0690
IS - 9
ER -