Interfacially formed poly(N,N-dimethylaminoethyl methacrylate)/polysulfone composite membranes for CO2/N2 separation

Runhong Du, Amit Chakma, Xianshe Feng

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Interfacially formed poly(N,N-dimethylaminoethyl methacrylate)/polysulfone (PDMAEMA/PSF) composite membranes were developed for CO2/N2 separation. A layer of PDMAEMA was deposited on a microporous PSF substrate by the solution coating technique, followed by crosslinking with p-xylylene dichloride (XDC) at the interface between the PDMAEMA solid layer and the crosslinking solution. The hydrophilicity and surface free energy of the membranes were analyzed by contact angle measurements with different probe liquids. The permselectivity of the membrane was shown to be affected by the PDMAEMA deposition time, interfacial crosslinking reaction time, and the PDMAEMA and XDC concentrations in the polymer coating solution and the crosslinking solution, respectively. The composite membrane showed a CO2 permeance of 85 GPU and a CO2/N2 ideal separation factor of 50 at 23 °C and 0.41 MPa of CO2 feed pressure.

Original languageEnglish
Pages (from-to)19-28
Number of pages10
JournalJournal of Membrane Science
Volume290
Issue number1-2
DOIs
Publication statusPublished - 1 Mar 2007
Externally publishedYes

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