Identification of the Water Amidogen Radical Complex

Courtney Ennis; J.R. Lane; H.G. Kjaergaard; Allan Mckinley

doi:10.1021/ja808109m

Identification of the Water Amidogen Radical Complex

Courtney Ennis, J.R. Lane, H.G. Kjaergaard, Allan Mckinley

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

Original language	English
Pages (from-to)	1358-1359
Journal	Journal of the Amercian Chemical Society
Volume	131
Issue number	4
DOIs	https://doi.org/10.1021/ja808109m
Publication status	Published - 2009

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10.1021/ja808109m

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title = "Identification of the Water Amidogen Radical Complex",

abstract = "The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.",

author = "Courtney Ennis and J.R. Lane and H.G. Kjaergaard and Allan Mckinley",

year = "2009",

doi = "10.1021/ja808109m",

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volume = "131",

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journal = "Journal of the Amercian Chemical Society",

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T1 - Identification of the Water Amidogen Radical Complex

AU - Ennis, Courtney

AU - Lane, J.R.

AU - Kjaergaard, H.G.

AU - Mckinley, Allan

PY - 2009

Y1 - 2009

N2 - The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

AB - The water amidogen radical complex (H2O−NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O−NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

U2 - 10.1021/ja808109m

DO - 10.1021/ja808109m

M3 - Article

C2 - 19173661

VL - 131

SP - 1358

EP - 1359

JO - Journal of the Amercian Chemical Society

JF - Journal of the Amercian Chemical Society

SN - 0002-7863

IS - 4

ER -

Identification of the Water Amidogen Radical Complex

Abstract

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