Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates

Lydia Wrobel, Tobias Rueffer, Marcus Korb, Harald Krautscheid, Jens Meyer, Philip C. Andrews, Heinrich Lang, Michael Mehring

Research output: Contribution to journalArticle

Abstract

The synthesis and characterization of six homo- and heteroleptic coordination polymers and oxido clusters of bismuth(III) vinylsulfonates are reported. The solvent-mediated reaction of BiPh3 and vinylsulfonic acid in ethanol produces [{Ph2Bi(O3SCH=CH2)}(n)] (1), which crystallizes as a one-dimensional coordination polymer as a result of bridging sulfonato ligands accompanied by intermolecular Bi center dot center dot center dot pi(arene) London dispersion interactions. In solution, compound 1 equilibrates to give [{PhBi(O3SCH=CH2)(2)}(n)] (2) and BiPh3. Compound 2 is obtained as a single product by the reaction of BiPh3 with vinylsulfonic acid in acetonitrile and crystallizes as a one-dimensional coordination polymer. The homoleptic vinylsulfonate [{Bi(O3SCH=CH2)(3)}(n)] (3) was isolated as a two-dimensional coordination polymer, which is quite moisture sensitive, but did not provide a distinct polynuclear bismuth oxido cluster upon hydrolysis. However, by treatment of [Bi6O4(OH)(4)(NO3)(6)]center dot H2O or [Bi38O45(OMc)(24)(dmso)(9)(H2O)(2)]center dot 2 DMSO center dot 5 H2O (OMc=methacrylate) with vinylsulfonic acid, such a cluster, namely, [Bi9O7(OH)(O3SCH=CH2)(11)(dmso)(11)](O3SCH=CH2)center dot 3 DMSO (4), is available as the main product. Starting from the hexanuclear bismuth oxido nitrate, another cluster, [Bi38O45(NO3)(8)(O3SCH=CH2)(14)(dmso)(18)](O3SCH=CH2)(2)center dot 2 DMSO (5), was observed as a co-crystallizing side product, which upon further hydrolysis afforded [Bi38O45(NO3)(6)(OH)(4)(O3SCH=CH2)(12)(dmso)(23)(H2O)(2)](O3SCH=CH2)(2)center dot 2 H2O (6).

Original languageEnglish
Pages (from-to)16630-16644
Number of pages15
JournalCHEMISTRY-A EUROPEAN JOURNAL
Volume24
Issue number62
DOIs
Publication statusPublished - 7 Nov 2018
Externally publishedYes

Cite this

Wrobel, L., Rueffer, T., Korb, M., Krautscheid, H., Meyer, J., Andrews, P. C., ... Mehring, M. (2018). Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates. CHEMISTRY-A EUROPEAN JOURNAL, 24(62), 16630-16644. https://doi.org/10.1002/chem.201803664
Wrobel, Lydia ; Rueffer, Tobias ; Korb, Marcus ; Krautscheid, Harald ; Meyer, Jens ; Andrews, Philip C. ; Lang, Heinrich ; Mehring, Michael. / Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates. In: CHEMISTRY-A EUROPEAN JOURNAL. 2018 ; Vol. 24, No. 62. pp. 16630-16644.
@article{6ff67f2c0f07424c82752147441505bf,
title = "Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates",
abstract = "The synthesis and characterization of six homo- and heteroleptic coordination polymers and oxido clusters of bismuth(III) vinylsulfonates are reported. The solvent-mediated reaction of BiPh3 and vinylsulfonic acid in ethanol produces [{Ph2Bi(O3SCH=CH2)}(n)] (1), which crystallizes as a one-dimensional coordination polymer as a result of bridging sulfonato ligands accompanied by intermolecular Bi center dot center dot center dot pi(arene) London dispersion interactions. In solution, compound 1 equilibrates to give [{PhBi(O3SCH=CH2)(2)}(n)] (2) and BiPh3. Compound 2 is obtained as a single product by the reaction of BiPh3 with vinylsulfonic acid in acetonitrile and crystallizes as a one-dimensional coordination polymer. The homoleptic vinylsulfonate [{Bi(O3SCH=CH2)(3)}(n)] (3) was isolated as a two-dimensional coordination polymer, which is quite moisture sensitive, but did not provide a distinct polynuclear bismuth oxido cluster upon hydrolysis. However, by treatment of [Bi6O4(OH)(4)(NO3)(6)]center dot H2O or [Bi38O45(OMc)(24)(dmso)(9)(H2O)(2)]center dot 2 DMSO center dot 5 H2O (OMc=methacrylate) with vinylsulfonic acid, such a cluster, namely, [Bi9O7(OH)(O3SCH=CH2)(11)(dmso)(11)](O3SCH=CH2)center dot 3 DMSO (4), is available as the main product. Starting from the hexanuclear bismuth oxido nitrate, another cluster, [Bi38O45(NO3)(8)(O3SCH=CH2)(14)(dmso)(18)](O3SCH=CH2)(2)center dot 2 DMSO (5), was observed as a co-crystallizing side product, which upon further hydrolysis afforded [Bi38O45(NO3)(6)(OH)(4)(O3SCH=CH2)(12)(dmso)(23)(H2O)(2)](O3SCH=CH2)(2)center dot 2 H2O (6).",
keywords = "bismuth, coordination polymers, oxido clusters, structure elucidation, vinylsulfonates, GROUP VB ELEMENTS, ACRYLIC BONE CEMENTS, RAY-POWDER DIFFRACTION, DISPERSION TYPE METAL, PI-ARENE INTERACTION, X-RAY, INFRARED-SPECTRA, HELICOBACTER-PYLORI, CRYSTAL-STRUCTURE, TRIPHENYL BISMUTH",
author = "Lydia Wrobel and Tobias Rueffer and Marcus Korb and Harald Krautscheid and Jens Meyer and Andrews, {Philip C.} and Heinrich Lang and Michael Mehring",
year = "2018",
month = "11",
day = "7",
doi = "10.1002/chem.201803664",
language = "English",
volume = "24",
pages = "16630--16644",
journal = "CHEMISTRY-A EUROPEAN JOURNAL",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag GmbH & Co. KGaA",
number = "62",

}

Wrobel, L, Rueffer, T, Korb, M, Krautscheid, H, Meyer, J, Andrews, PC, Lang, H & Mehring, M 2018, 'Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates' CHEMISTRY-A EUROPEAN JOURNAL, vol. 24, no. 62, pp. 16630-16644. https://doi.org/10.1002/chem.201803664

Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates. / Wrobel, Lydia; Rueffer, Tobias; Korb, Marcus; Krautscheid, Harald; Meyer, Jens; Andrews, Philip C.; Lang, Heinrich; Mehring, Michael.

In: CHEMISTRY-A EUROPEAN JOURNAL, Vol. 24, No. 62, 07.11.2018, p. 16630-16644.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Homo- and Heteroleptic Coordination Polymers and Oxido Clusters of Bismuth(III) Vinylsulfonates

AU - Wrobel, Lydia

AU - Rueffer, Tobias

AU - Korb, Marcus

AU - Krautscheid, Harald

AU - Meyer, Jens

AU - Andrews, Philip C.

AU - Lang, Heinrich

AU - Mehring, Michael

PY - 2018/11/7

Y1 - 2018/11/7

N2 - The synthesis and characterization of six homo- and heteroleptic coordination polymers and oxido clusters of bismuth(III) vinylsulfonates are reported. The solvent-mediated reaction of BiPh3 and vinylsulfonic acid in ethanol produces [{Ph2Bi(O3SCH=CH2)}(n)] (1), which crystallizes as a one-dimensional coordination polymer as a result of bridging sulfonato ligands accompanied by intermolecular Bi center dot center dot center dot pi(arene) London dispersion interactions. In solution, compound 1 equilibrates to give [{PhBi(O3SCH=CH2)(2)}(n)] (2) and BiPh3. Compound 2 is obtained as a single product by the reaction of BiPh3 with vinylsulfonic acid in acetonitrile and crystallizes as a one-dimensional coordination polymer. The homoleptic vinylsulfonate [{Bi(O3SCH=CH2)(3)}(n)] (3) was isolated as a two-dimensional coordination polymer, which is quite moisture sensitive, but did not provide a distinct polynuclear bismuth oxido cluster upon hydrolysis. However, by treatment of [Bi6O4(OH)(4)(NO3)(6)]center dot H2O or [Bi38O45(OMc)(24)(dmso)(9)(H2O)(2)]center dot 2 DMSO center dot 5 H2O (OMc=methacrylate) with vinylsulfonic acid, such a cluster, namely, [Bi9O7(OH)(O3SCH=CH2)(11)(dmso)(11)](O3SCH=CH2)center dot 3 DMSO (4), is available as the main product. Starting from the hexanuclear bismuth oxido nitrate, another cluster, [Bi38O45(NO3)(8)(O3SCH=CH2)(14)(dmso)(18)](O3SCH=CH2)(2)center dot 2 DMSO (5), was observed as a co-crystallizing side product, which upon further hydrolysis afforded [Bi38O45(NO3)(6)(OH)(4)(O3SCH=CH2)(12)(dmso)(23)(H2O)(2)](O3SCH=CH2)(2)center dot 2 H2O (6).

AB - The synthesis and characterization of six homo- and heteroleptic coordination polymers and oxido clusters of bismuth(III) vinylsulfonates are reported. The solvent-mediated reaction of BiPh3 and vinylsulfonic acid in ethanol produces [{Ph2Bi(O3SCH=CH2)}(n)] (1), which crystallizes as a one-dimensional coordination polymer as a result of bridging sulfonato ligands accompanied by intermolecular Bi center dot center dot center dot pi(arene) London dispersion interactions. In solution, compound 1 equilibrates to give [{PhBi(O3SCH=CH2)(2)}(n)] (2) and BiPh3. Compound 2 is obtained as a single product by the reaction of BiPh3 with vinylsulfonic acid in acetonitrile and crystallizes as a one-dimensional coordination polymer. The homoleptic vinylsulfonate [{Bi(O3SCH=CH2)(3)}(n)] (3) was isolated as a two-dimensional coordination polymer, which is quite moisture sensitive, but did not provide a distinct polynuclear bismuth oxido cluster upon hydrolysis. However, by treatment of [Bi6O4(OH)(4)(NO3)(6)]center dot H2O or [Bi38O45(OMc)(24)(dmso)(9)(H2O)(2)]center dot 2 DMSO center dot 5 H2O (OMc=methacrylate) with vinylsulfonic acid, such a cluster, namely, [Bi9O7(OH)(O3SCH=CH2)(11)(dmso)(11)](O3SCH=CH2)center dot 3 DMSO (4), is available as the main product. Starting from the hexanuclear bismuth oxido nitrate, another cluster, [Bi38O45(NO3)(8)(O3SCH=CH2)(14)(dmso)(18)](O3SCH=CH2)(2)center dot 2 DMSO (5), was observed as a co-crystallizing side product, which upon further hydrolysis afforded [Bi38O45(NO3)(6)(OH)(4)(O3SCH=CH2)(12)(dmso)(23)(H2O)(2)](O3SCH=CH2)(2)center dot 2 H2O (6).

KW - bismuth

KW - coordination polymers

KW - oxido clusters

KW - structure elucidation

KW - vinylsulfonates

KW - GROUP VB ELEMENTS

KW - ACRYLIC BONE CEMENTS

KW - RAY-POWDER DIFFRACTION

KW - DISPERSION TYPE METAL

KW - PI-ARENE INTERACTION

KW - X-RAY

KW - INFRARED-SPECTRA

KW - HELICOBACTER-PYLORI

KW - CRYSTAL-STRUCTURE

KW - TRIPHENYL BISMUTH

U2 - 10.1002/chem.201803664

DO - 10.1002/chem.201803664

M3 - Article

VL - 24

SP - 16630

EP - 16644

JO - CHEMISTRY-A EUROPEAN JOURNAL

JF - CHEMISTRY-A EUROPEAN JOURNAL

SN - 0947-6539

IS - 62

ER -