TY - JOUR
T1 - High-pressure polymorphism of cyclopentanol (C5H10O)
T2 - The structure of cyclopentanol phase-V at 1.5 GPa
AU - Moggach, S. A.
AU - Allan, D. R.
AU - Lozano-Casal, P.
AU - Parsons, S.
PY - 2005/9/1
Y1 - 2005/9/1
N2 - The fully ordered high-pressure crystal structure of cyclopentanol (C 5H10O) has been solved using single-crystal X-ray diffraction techniques on station 9.8 at the SRS Daresbury Laboratory. At pressures above 1.5 GPa, cyclopentanol crystallizes in the monoclinic P2 1/c space group with a = 17.882 (3), b = 5.4573 (3), c = 9.6817 (14) Å, β= 104.699 (8)° and Z′ = 2. The crystal structure is characterized by the formation of hydrogen-bonded molecular chains, denoted C22(4) in graph set notation, which lie parallel to the crystallographic c-axis, with the molecules adopting a pseudo fourfold arrangement around the central core of hydrogen bonds.
AB - The fully ordered high-pressure crystal structure of cyclopentanol (C 5H10O) has been solved using single-crystal X-ray diffraction techniques on station 9.8 at the SRS Daresbury Laboratory. At pressures above 1.5 GPa, cyclopentanol crystallizes in the monoclinic P2 1/c space group with a = 17.882 (3), b = 5.4573 (3), c = 9.6817 (14) Å, β= 104.699 (8)° and Z′ = 2. The crystal structure is characterized by the formation of hydrogen-bonded molecular chains, denoted C22(4) in graph set notation, which lie parallel to the crystallographic c-axis, with the molecules adopting a pseudo fourfold arrangement around the central core of hydrogen bonds.
KW - High pressure
KW - Single-crystal diffraction
KW - Small-molecule
UR - http://www.scopus.com/inward/record.url?scp=27644530022&partnerID=8YFLogxK
U2 - 10.1107/S0909049505021461
DO - 10.1107/S0909049505021461
M3 - Article
AN - SCOPUS:27644530022
SN - 0909-0495
VL - 12
SP - 590
EP - 597
JO - Journal of Synchrotron Radiation
JF - Journal of Synchrotron Radiation
IS - 5
ER -