Goodbye to S2- in aqueous solution

P. M. May; D. Batka; G. Hefter; E. Königsberger; D. Rowland

doi:10.1039/c8cc00187a

Goodbye to S^2- in aqueous solution

P. M. May, D. Batka, G. Hefter, E. Königsberger, D. Rowland

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

New Raman spectra of Na₂S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S^2-(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S^2-(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.

Original language	English
Pages (from-to)	1980-1983
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	16
DOIs	https://doi.org/10.1039/c8cc00187a
Publication status	Published - 1 Jan 2018

Access to Document

10.1039/c8cc00187a

Cite this

@article{096e1702b26340a595b57d7f11246f12,

title = "Goodbye to S2- in aqueous solution",

abstract = "New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2-(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2-(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.",

author = "May, {P. M.} and D. Batka and G. Hefter and E. K{\"o}nigsberger and D. Rowland",

year = "2018",

month = jan,

day = "1",

doi = "10.1039/c8cc00187a",

language = "English",

volume = "54",

pages = "1980--1983",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "16",

}

TY - JOUR

T1 - Goodbye to S2- in aqueous solution

AU - May, P. M.

AU - Batka, D.

AU - Hefter, G.

AU - Königsberger, E.

AU - Rowland, D.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2-(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2-(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.

AB - New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2-(aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2-(aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.

UR - http://www.scopus.com/inward/record.url?scp=85042458842&partnerID=8YFLogxK

U2 - 10.1039/c8cc00187a

DO - 10.1039/c8cc00187a

M3 - Article

C2 - 29404555

AN - SCOPUS:85042458842

SN - 1359-7345

VL - 54

SP - 1980

EP - 1983

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Goodbye to S^2- in aqueous solution

Abstract

Access to Document

Other files and links

Fingerprint

Cite this