Glutamic Acid Dendrimers Attached to a Central Ferrocene Core: Synthesis and Properties

F.E. Appoh; Donald Thomas; H.B. Kraatz

doi:10.1021/ma050531d

Glutamic Acid Dendrimers Attached to a Central Ferrocene Core: Synthesis and Properties

F.E. Appoh, Donald Thomas, H.B. Kraatz

School of Molecular Sciences

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.

Original language	English
Pages (from-to)	7562-7570
Journal	Macromolecules
Volume	38
DOIs	https://doi.org/10.1021/ma050531d
Publication status	Published - 2005

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title = "Glutamic Acid Dendrimers Attached to a Central Ferrocene Core: Synthesis and Properties",

abstract = "The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.",

author = "F.E. Appoh and Donald Thomas and H.B. Kraatz",

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AU - Appoh, F.E.

AU - Thomas, Donald

AU - Kraatz, H.B.

PY - 2005

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N2 - The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.

AB - The first synthesis of a series of glutamic acid based dendrimers having a central ferrocene core is described. The materials were fully characterized spectroscopically and display strong intramolecular H-bonding. This H-bonding can be disrupted with DMSO. The redox properties of the core are attenuated by the increase in the peptide dendritic sphere. But even at generation 6, there is communication between the exterior and the redox core.

U2 - 10.1021/ma050531d

DO - 10.1021/ma050531d

M3 - Article

VL - 38

SP - 7562

EP - 7570

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

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