TY - JOUR
T1 - Functionalization of Cage Amines with Pendant Aromatic and Heteroaromatic Substituents
AU - Donnelly, P.S.
AU - Harrowfield, J.M.
AU - Jeong, S-H.
AU - Mocerino, M.
AU - Skelton, B.W.
AU - White, A.H.
AU - Williams, C.C.
AU - Choi, Brian
AU - Zeng, Allan
AU - Burnet, S.
AU - Ivanova, I.
PY - 2001
Y1 - 2001
N2 - Structural studies have confirmed that it is possible to exploit the relatively low nucleophilicity of the "external" amino substituents on the Co-III complex of 1,8-diaminosarcophagine ("sarcophagine" = sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]-icosane) in acylation and alkylation reactions leading to a variety of functionalized cage amine complexes. With the appropriate choice of solvent, all these reactions can be conducted with high efficiency, and the new complexes display properties foreshadowing the application of cage systems in, for example, electroactive polymers.
AB - Structural studies have confirmed that it is possible to exploit the relatively low nucleophilicity of the "external" amino substituents on the Co-III complex of 1,8-diaminosarcophagine ("sarcophagine" = sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]-icosane) in acylation and alkylation reactions leading to a variety of functionalized cage amine complexes. With the appropriate choice of solvent, all these reactions can be conducted with high efficiency, and the new complexes display properties foreshadowing the application of cage systems in, for example, electroactive polymers.
U2 - 10.1002/1099-0682(200107)2001:7<1869::AID-EJIC1869>3.0.CO;2-A
DO - 10.1002/1099-0682(200107)2001:7<1869::AID-EJIC1869>3.0.CO;2-A
M3 - Article
SN - 1434-1948
VL - 2001
SP - 1869
EP - 1881
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
ER -