Five oxidation states in metal-bonded C-4 chains

MI Bruce; LI Denisovich; PJ Low; SM Peregudova; NA Ustynuk

Five oxidation states in metal-bonded C-4 chains

MI Bruce, LI Denisovich, PJ Low, SM Peregudova, NA Ustynuk

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

58 Citations (Web of Science)

Abstract

The 36-electron diruthenium buta-1,3-diynyl complexes [Ru]C=C-C=C[Ru] [Ru = Ru(PPh(3))(2)Cp and Ru(PMe(3))(PPh(3))Cp] undergo four stepwise one-electron oxidation-reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.

Original language	English
Pages (from-to)	200-201
Number of pages	2
Journal	Mendeleev Communications
Issue number	5
Publication status	Published - Sept 1996

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title = "Five oxidation states in metal-bonded C-4 chains",

abstract = "The 36-electron diruthenium buta-1,3-diynyl complexes [Ru]C=C-C=C[Ru] [Ru = Ru(PPh(3))(2)Cp and Ru(PMe(3))(PPh(3))Cp] undergo four stepwise one-electron oxidation-reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.",

keywords = "CARBON, RUTHENIUM, COMPLEXES, CHARGE",

author = "MI Bruce and LI Denisovich and PJ Low and SM Peregudova and NA Ustynuk",

year = "1996",

month = sep,

language = "English",

pages = "200--201",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "ROYAL SOC CHEMISTRY",

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T1 - Five oxidation states in metal-bonded C-4 chains

AU - Bruce, MI

AU - Denisovich, LI

AU - Low, PJ

AU - Peregudova, SM

AU - Ustynuk, NA

PY - 1996/9

Y1 - 1996/9

N2 - The 36-electron diruthenium buta-1,3-diynyl complexes [Ru]C=C-C=C[Ru] [Ru = Ru(PPh(3))(2)Cp and Ru(PMe(3))(PPh(3))Cp] undergo four stepwise one-electron oxidation-reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.

AB - The 36-electron diruthenium buta-1,3-diynyl complexes [Ru]C=C-C=C[Ru] [Ru = Ru(PPh(3))(2)Cp and Ru(PMe(3))(PPh(3))Cp] undergo four stepwise one-electron oxidation-reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.

KW - CARBON

KW - RUTHENIUM

KW - COMPLEXES

KW - CHARGE

M3 - Article

SN - 0959-9436

SP - 200

EP - 201

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 5

ER -

Five oxidation states in metal-bonded C-4 chains

Abstract

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