Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes

Research output: Contribution to journalArticle

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Abstract

In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.
Original languageEnglish
Pages (from-to)1842-1853
JournalAustralian Journal of Chemistry
Volume68
Issue number12
DOIs
Publication statusPublished - 2015

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phosphine
Phosphites
Nickel
Ammonia
Functional groups
Catalysts

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title = "Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes",
abstract = "In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.",
author = "Sven Kampmann and Nikki Man and Allan Mckinley and George Koutsantonis and Scott Stewart",
year = "2015",
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language = "English",
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pages = "1842--1853",
journal = "Australian Journal of Chemistry:an international journal for chemical science",
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Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes. / Kampmann, Sven; Man, Nikki; Mckinley, Allan; Koutsantonis, George; Stewart, Scott.

In: Australian Journal of Chemistry, Vol. 68, No. 12, 2015, p. 1842-1853.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes

AU - Kampmann, Sven

AU - Man, Nikki

AU - Mckinley, Allan

AU - Koutsantonis, George

AU - Stewart, Scott

PY - 2015

Y1 - 2015

N2 - In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.

AB - In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.

U2 - 10.1071/CH15459

DO - 10.1071/CH15459

M3 - Article

VL - 68

SP - 1842

EP - 1853

JO - Australian Journal of Chemistry:an international journal for chemical science

JF - Australian Journal of Chemistry:an international journal for chemical science

SN - 0004-9425

IS - 12

ER -