TY - JOUR
T1 - Exploring the Catalytic Reactivity of Nickel Phosphine-Phosphite Complexes
AU - Kampmann, Sven
AU - Man, Nikki
AU - Mckinley, Allan
AU - Koutsantonis, George
AU - Stewart, Scott
PY - 2015
Y1 - 2015
N2 - In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.
AB - In this study, we present an investigation into various nickel phosphite and phosphite-phosphine complexes for use in the Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions and the ammonia arylation reaction. In these coupling reactions, it was discovered that the Ni[P(OEt)3]4, (dppf)Ni[P(OPh)3]2, and (binap)Ni[P(OPh)3]2 catalysts were the most effective. In addition, an optimisation process for these catalytic systems as well as functional group compatibility are discussed.
U2 - 10.1071/CH15459
DO - 10.1071/CH15459
M3 - Article
VL - 68
SP - 1842
EP - 1853
JO - Australian Journal of Chemistry:an international journal for chemical science
JF - Australian Journal of Chemistry:an international journal for chemical science
SN - 0004-9425
IS - 12
ER -