Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

D.J. Nielsen; A.M. Magill; B.F. Yates; K.J. Cavell; Brian Skelton; Allan White

doi:10.1039/b207020k

Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

D.J. Nielsen, A.M. Magill, B.F. Yates, K.J. Cavell, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

73 Citations (Scopus)

Abstract

Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

Original language	English
Pages (from-to)	2500-2501
Journal	Chemical Communications
Volume	n/a
Issue number	n/a
DOIs	https://doi.org/10.1039/b207020k
Publication status	Published - 2002

Access to Document

10.1039/b207020k

Cite this

@article{94609b5cb8744215b5d0ca6ca0e5d867,

title = "Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex",

abstract = "Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.",

author = "D.J. Nielsen and A.M. Magill and B.F. Yates and K.J. Cavell and Brian Skelton and Allan White",

year = "2002",

doi = "10.1039/b207020k",

language = "English",

volume = "n/a",

pages = "2500--2501",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "n/a",

}

TY - JOUR

T1 - Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

AU - Nielsen, D.J.

AU - Magill, A.M.

AU - Yates, B.F.

AU - Cavell, K.J.

AU - Skelton, Brian

AU - White, Allan

PY - 2002

Y1 - 2002

N2 - Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

AB - Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

UR - https://www.scopus.com/pages/publications/0036978752

U2 - 10.1039/b207020k

DO - 10.1039/b207020k

M3 - Article

SN - 1359-7345

VL - n/a

SP - 2500

EP - 2501

JO - Chemical Communications

JF - Chemical Communications

IS - n/a

ER -

Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

Abstract

Access to Document

Other files and links

Fingerprint

Cite this