Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

Brendan Graham, J.M. Harrowfield, R.D. Trengove, A.F. Lagalante, T.J. Bruno

Research output: Contribution to journalArticle

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Abstract

In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.
Original languageEnglish
Pages (from-to)179-182
JournalJournal of Inclusion Phenomena and Macrocyclic Chemistry
Volume43
Issue numbern/a
DOIs
Publication statusPublished - 2002

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dioxides
Carbon Dioxide
X-Ray Diffraction
Thermogravimetric analysis
carbon dioxide
Infrared spectroscopy
Spectrum Analysis
infrared spectroscopy
Nuclear magnetic resonance
Single crystals
inclusions
thermogravimetry
solid state
X ray diffraction
nuclear magnetic resonance
cavities
Molecules
single crystals
diffraction
X-ray diffraction

Cite this

Graham, Brendan ; Harrowfield, J.M. ; Trengove, R.D. ; Lagalante, A.F. ; Bruno, T.J. / Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide. In: Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2002 ; Vol. 43, No. n/a. pp. 179-182.
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Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide. / Graham, Brendan; Harrowfield, J.M.; Trengove, R.D.; Lagalante, A.F.; Bruno, T.J.

In: Journal of Inclusion Phenomena and Macrocyclic Chemistry, Vol. 43, No. n/a, 2002, p. 179-182.

Research output: Contribution to journalArticle

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T1 - Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

AU - Graham, Brendan

AU - Harrowfield, J.M.

AU - Trengove, R.D.

AU - Lagalante, A.F.

AU - Bruno, T.J.

PY - 2002

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AB - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

U2 - 10.1023/A:1021265822247

DO - 10.1023/A:1021265822247

M3 - Article

VL - 43

SP - 179

EP - 182

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 1388-3127

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ER -