TY - JOUR
T1 - Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide
AU - Graham, Brendan
AU - Harrowfield, J.M.
AU - Trengove, R.D.
AU - Lagalante, A.F.
AU - Bruno, T.J.
PY - 2002
Y1 - 2002
N2 - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.
AB - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.
U2 - 10.1023/A:1021265822247
DO - 10.1023/A:1021265822247
M3 - Article
VL - 43
SP - 179
EP - 182
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
SN - 1388-3127
IS - n/a
ER -