Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

Brendan Graham; J.M. Harrowfield; R.D. Trengove; A.F. Lagalante; T.J. Bruno

doi:10.1023/A:1021265822247

Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

Brendan Graham, J.M. Harrowfield, R.D. Trengove, A.F. Lagalante, T.J. Bruno

Chemical Engineering

Research output: Contribution to journal › Article

24 Citations (Scopus)

Abstract

In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

Original language	English
Pages (from-to)	179-182
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	43
Issue number	n/a
DOIs	https://doi.org/10.1023/A:1021265822247
Publication status	Published - 2002

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title = "Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide",

abstract = "In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.",

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AU - Graham, Brendan

AU - Harrowfield, J.M.

AU - Trengove, R.D.

AU - Lagalante, A.F.

AU - Bruno, T.J.

PY - 2002

Y1 - 2002

N2 - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

AB - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

U2 - 10.1023/A:1021265822247

DO - 10.1023/A:1021265822247

M3 - Article

VL - 43

SP - 179

EP - 182

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 1388-3127

IS - n/a

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