Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

Brendan Graham; J.M. Harrowfield; R.D. Trengove; A.F. Lagalante; T.J. Bruno

doi:10.1023/A:1021265822247

Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide

Brendan Graham, J.M. Harrowfield, R.D. Trengove, A.F. Lagalante, T.J. Bruno

Chemical Engineering

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23 Citations (Scopus)

Abstract

In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

Original language	English
Pages (from-to)	179-182
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	43
Issue number	n/a
DOIs	https://doi.org/10.1023/A:1021265822247
Publication status	Published - 2002

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Graham, B., Harrowfield, J. M., Trengove, R. D., Lagalante, A. F., & Bruno, T. J. (2002). Evidence of a Host:Guest Complex between p-t-Butylcalix[4]arene and Carbon Dioxide. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 43(n/a), 179-182. https://doi.org/10.1023/A:1021265822247

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AU - Lagalante, A.F.

AU - Bruno, T.J.

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AB - In this paper we report evidence for an inclusion complex between carbon dioxide and p-t-butylcalix[4] arene. The complex was studied with infrared spectroscopy, single-crystal X-ray diffraction, solid-state NMR, and thermogravimetric analysis. Results indicate that 70% of the p-t-butylcalix[ 4] arene cavities could be occupied by a CO2 molecule following exposure at 30 MPa and 40degreesC.

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10.1023/A:1021265822247