Equilibrium Adsorption Measurements of Pure Nitrogen, Carbon Dioxide, and Methane on a Carbon Molecular Sieve at Cryogenic Temperatures and High Pressures

Guillaume Watson, Eric May, Brendan Graham, M.A. Trebble, R.D. Trengrove, K.I. Chan

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Abstract

A detailed experimental study of the adsorption behavior at equilibrium of pure nitrogen, methane, and carbon dioxide gases on a commercial carbon molecular sieve (Shirasagi MSC 3K-161) is reported at temperatures between 115 K to 323 K and pressures up to 5 MPa. A volumetric-type apparatus was used to obtain over 200 excess (Gibbs) adsorption capacity data over this range of pressure and temperature with an estimated uncertainty of 4 %. The absolute adsorption isotherms were type I in the IUPAC classification with the adsorption capacity at constant pressure increasing significantly with decreasing temperature. For each gas, the adsorption data were regressed to a four parameter Toth equation to represent the temperature and pressure dependence of the data with a relative standard uncertainty of 4 %. The optimized parameters from the Toth equation included the isosteric enthalpies of adsorption that were 17 kJ·mol−1, 27 kJ·mol−1, and 18 kJ·mol−1 for N2, CO2, and CH4, respectively.
Original languageEnglish
Pages (from-to)2701-2707
JournalJournal of Chemical and Engineering Data
Volume54
Issue number9
DOIs
Publication statusPublished - 2009

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