A detailed experimental study of the adsorption behavior at equilibrium of pure nitrogen, methane, and carbon dioxide gases on a commercial carbon molecular sieve (Shirasagi MSC 3K-161) is reported at temperatures between 115 K to 323 K and pressures up to 5 MPa. A volumetric-type apparatus was used to obtain over 200 excess (Gibbs) adsorption capacity data over this range of pressure and temperature with an estimated uncertainty of 4 %. The absolute adsorption isotherms were type I in the IUPAC classification with the adsorption capacity at constant pressure increasing significantly with decreasing temperature. For each gas, the adsorption data were regressed to a four parameter Toth equation to represent the temperature and pressure dependence of the data with a relative standard uncertainty of 4 %. The optimized parameters from the Toth equation included the isosteric enthalpies of adsorption that were 17 kJ·mol−1, 27 kJ·mol−1, and 18 kJ·mol−1 for N2, CO2, and CH4, respectively.
Watson, G., May, E., Graham, B., Trebble, M. A., Trengrove, R. D., & Chan, K. I. (2009). Equilibrium Adsorption Measurements of Pure Nitrogen, Carbon Dioxide, and Methane on a Carbon Molecular Sieve at Cryogenic Temperatures and High Pressures. Journal of Chemical and Engineering Data, 54(9), 2701-2707. https://doi.org/10.1021/je900224w