Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Mohamed Makha; Colin Raston; Alexandre Sobolev; L.J. Barbour; P. Turner

doi:10.1039/b600550k

Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Mohamed Makha, Colin Raston, Alexandre Sobolev, L.J. Barbour, P. Turner

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

p-Benzylcalix[4] arene forms inclusion complexes with o-carborane and C-60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 angstrom; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.

Original language	English
Pages (from-to)	306-308
Journal	CrystEngComm
Volume	8
Issue number	4
DOIs	https://doi.org/10.1039/b600550k
Publication status	Published - 2006

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abstract = "p-Benzylcalix[4] arene forms inclusion complexes with o-carborane and C-60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 angstrom; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.",

author = "Mohamed Makha and Colin Raston and Alexandre Sobolev and L.J. Barbour and P. Turner",

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AU - Turner, P.

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AB - p-Benzylcalix[4] arene forms inclusion complexes with o-carborane and C-60 wherein the icosahedral molecules reside endo or exo relative to the calixarene cavity with the threshold for endo vs. exo binding lying between 8.1 and 10.0 angstrom; in the extended structures the o-carboranes are arranged in 'pairs' whereas the fullerenes are packed into novel flat sheets with each calixarene nestled into a cavity created by a square array of fullerenes.

U2 - 10.1039/b600550k

DO - 10.1039/b600550k

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ER -

Endo- versus exo-cavity interplay of p-benzylcalix[4]arene with spheroidal molecules

Abstract

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