TY - JOUR
T1 - Dimethylsuphoxide and its roles in the coordination chemistry of the uranyl ion
AU - Harrowfield, J.M.
AU - Skelton, Brian
AU - White, Allan
PY - 2005
Y1 - 2005
N2 - Structure determinations for the dimethylsulphoxide (DMSO) solvates of uranyl triflate, nitrate, picrate and a tetranuclear basic acetate show DMSO to be bound in all cases as an O-donor ligand but with the sulphur atoms involved in a variety of close approaches which may be significant in determining details of the complex ion structures. These close approaches, which generally mean that S may be considered to have '3 + 2'coordination, usually involve 0 of an adjacent DMSO or oxyanion ligand, but can also involve uranyl-O and can be both intra- and inter-molecular. To cite this article: J.M. Harrowfield et al., C. R. Chimie 8 (2005). (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.
AB - Structure determinations for the dimethylsulphoxide (DMSO) solvates of uranyl triflate, nitrate, picrate and a tetranuclear basic acetate show DMSO to be bound in all cases as an O-donor ligand but with the sulphur atoms involved in a variety of close approaches which may be significant in determining details of the complex ion structures. These close approaches, which generally mean that S may be considered to have '3 + 2'coordination, usually involve 0 of an adjacent DMSO or oxyanion ligand, but can also involve uranyl-O and can be both intra- and inter-molecular. To cite this article: J.M. Harrowfield et al., C. R. Chimie 8 (2005). (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.
U2 - 10.1016/j.crci.2004.10.009
DO - 10.1016/j.crci.2004.10.009
M3 - Article
SN - 1631-0748
VL - 8
SP - 169
EP - 180
JO - Comptes Rendus. Chimie
JF - Comptes Rendus. Chimie
IS - 2
ER -