Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

BD James; J Mrozinski; J Klak; Brian Skelton; Allan White

doi:10.1002/zaac.200700019

Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

BD James, J Mrozinski, J Klak, Brian Skelton, Allan White

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6 Citations (Scopus)

Abstract

Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.

Original language	English
Pages (from-to)	974-978
Journal	Zeitschrift fuer Anorganische und Allgemeine Chemie
Volume	633
Issue number	7
DOIs	https://doi.org/10.1002/zaac.200700019
Publication status	Published - 2007

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title = "Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties",

abstract = "Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.",

author = "BD James and J Mrozinski and J Klak and Brian Skelton and Allan White",

year = "2007",

doi = "10.1002/zaac.200700019",

language = "English",

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journal = "Zeitschrift fuer Anorganische und Allgemeine Chemie",

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T1 - Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

AU - James, BD

AU - Mrozinski, J

AU - Klak, J

AU - Skelton, Brian

AU - White, Allan

PY - 2007

Y1 - 2007

N2 - Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.

AB - Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.

U2 - 10.1002/zaac.200700019

DO - 10.1002/zaac.200700019

M3 - Article

SN - 0044-2313

VL - 633

SP - 974

EP - 978

JO - Zeitschrift fuer Anorganische und Allgemeine Chemie

JF - Zeitschrift fuer Anorganische und Allgemeine Chemie

IS - 7

ER -

Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

Abstract

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