Diethylenetriammonium aquapentachloroferrate(III) chloride: Structure and magnetic properties

BD James, J Mrozinski, J Klak, Brian Skelton, Allan White

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)


Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH(3)) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen-bonded lattice. On cooling, the high spin Fe-III material shows weak antiferromagnetic coupling that results in a Neel temperature of 2.70 K.
Original languageEnglish
Pages (from-to)974-978
JournalZeitschrift fuer Anorganische und Allgemeine Chemie
Issue number7
Publication statusPublished - 2007


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