Dichloro(methanol-κO)[(methoxy)-tris(1 -methy l-1H-imidazol-2-yl)- methane-κ2N3]iron(II) (ca 153 K)

M.P. Batten; A.J. Canty; K.J. Cavell; T. Ruther; Brian Skelton; Allan White

doi:10.1107/S010827010401087X

Dichloro(methanol-κO)[(methoxy)-tris(1 -methy l-1H-imidazol-2-yl)- methane-κ2N3]iron(II) (ca 153 K)

M.P. Batten, A.J. Canty, K.J. Cavell, T. Ruther, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

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Abstract

In the quasi-trigonal-bipyramidal environment of the five-coordinate FeII atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) Å, Fe-N(equatorial) is 2.108 (2) Å and N-Fe-O is 174.14 (7)°.

Original language	English
Pages (from-to)	m314-m315
Journal	Acta Crystallographica Section C: Structural Chemistry
Volume	C60
Issue number	7
DOIs	https://doi.org/10.1107/S010827010401087X
Publication status	Published - 2004

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title = "Dichloro(methanol-κO)[(methoxy)-tris(1 -methy l-1H-imidazol-2-yl)- methane-κ2N3]iron(II) (ca 153 K)",

abstract = "In the quasi-trigonal-bipyramidal environment of the five-coordinate FeII atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) {\AA}, Fe-N(equatorial) is 2.108 (2) {\AA} and N-Fe-O is 174.14 (7)°.",

author = "M.P. Batten and A.J. Canty and K.J. Cavell and T. Ruther and Brian Skelton and Allan White",

year = "2004",

doi = "10.1107/S010827010401087X",

language = "English",

volume = "C60",

pages = "m314--m315",

journal = "Acta Crystallographica Section C: Structural Chemistry",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Dichloro(methanol-κO)[(methoxy)-tris(1 -methy l-1H-imidazol-2-yl)- methane-κ2N3]iron(II) (ca 153 K)

AU - Batten, M.P.

AU - Canty, A.J.

AU - Cavell, K.J.

AU - Ruther, T.

AU - Skelton, Brian

AU - White, Allan

PY - 2004

Y1 - 2004

N2 - In the quasi-trigonal-bipyramidal environment of the five-coordinate FeII atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) Å, Fe-N(equatorial) is 2.108 (2) Å and N-Fe-O is 174.14 (7)°.

AB - In the quasi-trigonal-bipyramidal environment of the five-coordinate FeII atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) Å, Fe-N(equatorial) is 2.108 (2) Å and N-Fe-O is 174.14 (7)°.

U2 - 10.1107/S010827010401087X

DO - 10.1107/S010827010401087X

M3 - Article

C2 - 15237145

SN - 0108-2701

VL - C60

SP - m314-m315

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

IS - 7

ER -

Dichloro(methanol-κO)[(methoxy)-tris(1 -methy l-1H-imidazol-2-yl)- methane-κ2N3]iron(II) (ca 153 K)

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