Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo; Jack K. Clegg; Louis M. Rendina

doi:10.1039/b700689f

Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo
, Jack K. Clegg
, Louis M. Rendina

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

Original language	English
Pages (from-to)	1982-1985
Number of pages	4
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b700689f
Publication status	Published - 2007
Externally published	Yes

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title = "Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions",

abstract = "The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.",

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year = "2007",

doi = "10.1039/b700689f",

language = "English",

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journal = "Dalton Transactions",

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publisher = "The Royal Society of Chemistry",

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T2 - Easy formation of nido-carborane phosphonium zwitterions

AU - Ioppolo, Joseph A.

AU - Clegg, Jack K.

AU - Rendina, Louis M.

PY - 2007

Y1 - 2007

N2 - The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

AB - The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

UR - https://www.scopus.com/pages/publications/34248681009

U2 - 10.1039/b700689f

DO - 10.1039/b700689f

M3 - Article

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AN - SCOPUS:34248681009

SN - 1477-9226

SP - 1982

EP - 1985

JO - Dalton Transactions

JF - Dalton Transactions

IS - 20

ER -

Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Abstract

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