Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo; Jack K. Clegg; Louis M. Rendina

doi:10.1039/b700689f

Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Joseph A. Ioppolo, Jack K. Clegg, Louis M. Rendina

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

Original language	English
Pages (from-to)	1982-1985
Number of pages	4
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b700689f
Publication status	Published - 2007
Externally published	Yes

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abstract = "The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.",

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AU - Rendina, Louis M.

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AB - The first examples of arylphosphonium salts containing a dicarba-closo-dodecaborane(12) (closo-carborane) are reported; in contrast to the 1,12-carborane derivative, the 1,2- and 1,7-isomers undergo a facile deboronation reaction in polar solvents to afford the corresponding nido-carborane phosphonium zwitterions.

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Dicarba-closo-dodecaborane(12) derivatives of phosphonium salts: Easy formation of nido-carborane phosphonium zwitterions

Abstract

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