Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane

John M. Gardiner; Marck Nørret; Ian H. Sadler

doi:10.1039/CC9960002709

Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane

John M. Gardiner, Marck Nørret, Ian H. Sadler

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis (and not the trans) isomer of 2,6-dimethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specific and an efficient kinetic resolution is achieved using AD.

Original language	English
Pages (from-to)	2709-2710
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/CC9960002709
Publication status	Published - 1 Jan 1996
Externally published	Yes

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title = "Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane",

abstract = "Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis (and not the trans) isomer of 2,6-dimethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specific and an efficient kinetic resolution is achieved using AD.",

author = "Gardiner, {John M.} and Marck N{\o}rret and Sadler, {Ian H.}",

year = "1996",

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doi = "10.1039/CC9960002709",

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T1 - Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane

AU - Gardiner, John M.

AU - Nørret, Marck

AU - Sadler, Ian H.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis (and not the trans) isomer of 2,6-dimethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specific and an efficient kinetic resolution is achieved using AD.

AB - Achiral dihydroxylation and catalytic asymmetric dihydroxylation (AD) lead to reaction of only the cis (and not the trans) isomer of 2,6-dimethylbenzylidenecyclohexane, dihydroxylation is diastereoisomer specific and an efficient kinetic resolution is achieved using AD.

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U2 - 10.1039/CC9960002709

DO - 10.1039/CC9960002709

M3 - Article

AN - SCOPUS:0344979435

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SP - 2709

EP - 2710

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Diastereospecific dihydroxylation and highly efficient asymmetric dihydroxylation kinetic resolution of cis/trans-2,6-dimethylbenzylidenecyclohexane

Abstract

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