TY - JOUR
T1 - Diaquabis(dimethyl sulfoxide)bis(3,5-dinitrobenzoato)zinc(II) and the synthesis of the Cu, Ni and Co analogs
AU - Miminoshvili, E.B.
AU - Sobolev, Alexandre
AU - Sakvarelidze, T.N.
AU - Miminoshvili, K.E.
AU - Kutelia, E.R.
PY - 2003
Y1 - 2003
N2 - In order to model processes of chemisorption in organic salts formed between dinitrobenzoic acids (DNBH) and secondary amines (R2NH), a series of compounds of composition [MII(3,5-DNB)2(DMSO)2(H2O)2] (where MII is Zn, Cu, Ni or Co, 3,5-DNB is the 3,5-dinitrobenzoate ion, and DMSO is dimethyl sulfoxide) have been prepared. In diaquabis(dimethyl sulfoxide)bis(3,5-DNB)zinc(II), [Zn(C7H3N2O6)2(C2H6OS)2(H2O)2], the 3,5-DNB ions and molecules of DMSO are monodentate ligands that are coordinated to the Zn atom through their O atoms. These ligands, together with two molecules of water, form a slightly distorted octahedral coordination environment for the Zn atom, which lies on a center of symmetry.
AB - In order to model processes of chemisorption in organic salts formed between dinitrobenzoic acids (DNBH) and secondary amines (R2NH), a series of compounds of composition [MII(3,5-DNB)2(DMSO)2(H2O)2] (where MII is Zn, Cu, Ni or Co, 3,5-DNB is the 3,5-dinitrobenzoate ion, and DMSO is dimethyl sulfoxide) have been prepared. In diaquabis(dimethyl sulfoxide)bis(3,5-DNB)zinc(II), [Zn(C7H3N2O6)2(C2H6OS)2(H2O)2], the 3,5-DNB ions and molecules of DMSO are monodentate ligands that are coordinated to the Zn atom through their O atoms. These ligands, together with two molecules of water, form a slightly distorted octahedral coordination environment for the Zn atom, which lies on a center of symmetry.
U2 - 10.1107/S0108270103003779
DO - 10.1107/S0108270103003779
M3 - Article
SN - 0108-2701
VL - 59
SP - m118-m120
JO - Acta Crystallographica Section C - Crystal Structure Communications
JF - Acta Crystallographica Section C - Crystal Structure Communications
IS - 4
ER -