Deoxygenation Prevents Arsenic Mobilization during Deepwell Injection into Sulfide-Bearing Aquifers

Henning Prommer, Jing Sun, Lauren Helm, Bhasker Rathi, Adam J. Siade, Ryan Morris

Research output: Contribution to journalArticle

Abstract

Coal seam gas (CSG) extraction generates large volumes of coproduced water. Injection of the excess water into deep aquifers is often the most sustainable management option. However, such injection risks undesired sediment–water interactions that mobilize metal(loid)s in the receiving aquifer. This risk can be mitigated through pretreatment of the injectant. Here, we conducted a sequence of three push–pull tests (PPTs) where the injectant was pretreated using acid amendment and/or deoxygenation to identify the processes controlling the fate of metal(loid)s and to understand the treatment requirements for large-scale CSG water injection. The injection and recovery cycles were closely monitored, followed by analysis of the observations through reactive transport modeling. While arsenic was mobilized in all three PPTs, significantly lower arsenic concentrations were observed in the recovered water when the injectant was deoxygenated, regardless of pH adjustment. The breakthrough of arsenic was commensurate with molybdenum, but distinct from phosphate. This allowed for the observed and modeled arsenic and molybdenum mobilization to be attributed to a stoichiometric codissolution process during pyrite oxidation, whereas phosphate mobility was governed by sorption. Understanding the nature of these hydrochemical processes explained the greater efficiency of pretreatment by deoxygenation on minimizing metal(loid) mobilization compared to the acid amendment.
Original languageEnglish
Pages (from-to)13801-13810
JournalEnvironmental Science & Technology
Volume52
Issue number23
DOIs
Publication statusPublished - 4 Dec 2018

Fingerprint

Bearings (structural)
Arsenic
Sulfides
Aquifers
mobilization
arsenic
sulfide
aquifer
Molybdenum
Metals
molybdenum
coal seam
Water
metal
Phosphates
phosphate
water
Acids
reactive transport
Water injection

Cite this

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title = "Deoxygenation Prevents Arsenic Mobilization during Deepwell Injection into Sulfide-Bearing Aquifers",
abstract = "Coal seam gas (CSG) extraction generates large volumes of coproduced water. Injection of the excess water into deep aquifers is often the most sustainable management option. However, such injection risks undesired sediment–water interactions that mobilize metal(loid)s in the receiving aquifer. This risk can be mitigated through pretreatment of the injectant. Here, we conducted a sequence of three push–pull tests (PPTs) where the injectant was pretreated using acid amendment and/or deoxygenation to identify the processes controlling the fate of metal(loid)s and to understand the treatment requirements for large-scale CSG water injection. The injection and recovery cycles were closely monitored, followed by analysis of the observations through reactive transport modeling. While arsenic was mobilized in all three PPTs, significantly lower arsenic concentrations were observed in the recovered water when the injectant was deoxygenated, regardless of pH adjustment. The breakthrough of arsenic was commensurate with molybdenum, but distinct from phosphate. This allowed for the observed and modeled arsenic and molybdenum mobilization to be attributed to a stoichiometric codissolution process during pyrite oxidation, whereas phosphate mobility was governed by sorption. Understanding the nature of these hydrochemical processes explained the greater efficiency of pretreatment by deoxygenation on minimizing metal(loid) mobilization compared to the acid amendment.",
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Deoxygenation Prevents Arsenic Mobilization during Deepwell Injection into Sulfide-Bearing Aquifers. / Prommer, Henning; Sun, Jing; Helm, Lauren; Rathi, Bhasker; Siade, Adam J.; Morris, Ryan.

In: Environmental Science & Technology, Vol. 52, No. 23, 04.12.2018, p. 13801-13810.

Research output: Contribution to journalArticle

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T1 - Deoxygenation Prevents Arsenic Mobilization during Deepwell Injection into Sulfide-Bearing Aquifers

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AU - Sun, Jing

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AU - Siade, Adam J.

AU - Morris, Ryan

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