Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes

M.I. Bruce; P. Hinterding; K. Mingzhe; P.J. Low; Brian Skelton; Allan White

doi:10.1039/a700663b

Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes

M.I. Bruce, P. Hinterding, K. Mingzhe, P.J. Low, Brian Skelton, Allan White

Research output: Contribution to journal › Article › peer-review

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Abstract

Reactions of aromatic imines with the putative butatrienylidene-ruthenium cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(C=CC(9)H(4)MeN)(PPh(3))(2)(eta-C5H5)] and [Ru{C=CC(CH=CHPh)=N(C6H4NO2-3)}(PPh(3))(2)(eta-C5H5)] are reported.

Original language	English
Pages (from-to)	715-716
Journal	Chemical Communications
Volume	N/A
DOIs	https://doi.org/10.1039/a700663b
Publication status	Published - 1997

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title = "Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes",

abstract = "Reactions of aromatic imines with the putative butatrienylidene-ruthenium cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(C=CC(9)H(4)MeN)(PPh(3))(2)(eta-C5H5)] and [Ru{C=CC(CH=CHPh)=N(C6H4NO2-3)}(PPh(3))(2)(eta-C5H5)] are reported.",

author = "M.I. Bruce and P. Hinterding and K. Mingzhe and P.J. Low and Brian Skelton and Allan White",

year = "1997",

doi = "10.1039/a700663b",

language = "English",

volume = "N/A",

pages = "715--716",

journal = "Chemical Communications, 2000",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

}

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T1 - Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes

AU - Bruce, M.I.

AU - Hinterding, P.

AU - Mingzhe, K.

AU - Low, P.J.

AU - Skelton, Brian

AU - White, Allan

PY - 1997

Y1 - 1997

N2 - Reactions of aromatic imines with the putative butatrienylidene-ruthenium cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(C=CC(9)H(4)MeN)(PPh(3))(2)(eta-C5H5)] and [Ru{C=CC(CH=CHPh)=N(C6H4NO2-3)}(PPh(3))(2)(eta-C5H5)] are reported.

AB - Reactions of aromatic imines with the putative butatrienylidene-ruthenium cation [Ru(C=C=C=CH2)(PPh(3))(2)(eta-C5H5)](+) gives complexes containing either 4-ethynylquinoline or 1-azabuta-1,3-diene ligands; the molecular structures of [Ru(C=CC(9)H(4)MeN)(PPh(3))(2)(eta-C5H5)] and [Ru{C=CC(CH=CHPh)=N(C6H4NO2-3)}(PPh(3))(2)(eta-C5H5)] are reported.

U2 - 10.1039/a700663b

DO - 10.1039/a700663b

M3 - Article

SN - 1359-7345

VL - N/A

SP - 715

EP - 716

JO - Chemical Communications, 2000

JF - Chemical Communications, 2000

ER -

Cycloaddition of aromatic imines to a ruthenium butatrienylidene complex: synthesis of 4-ethynylquinoline and 1-azabuta-1,3-diene complexes

Abstract

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