Crystal structure of bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) 0.39-hydrate

E.A. Buvaylo, O.Y. Vassilyeva, Brian Skelton

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3 Citations (Scopus)

Abstract

The title compound, [Mn(C12H15NO5)2]·0.39H2O, is a 0.39 hydrate of the isostructural complex bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) that has previously been reported by Back, Oliveira, Canabarro & Iglesias [Z. Anorg. Allg. Chem. (2015), 641, 941-947], based on room-temperature data. The current structure that was determined at 100 K reveals a lengthening of the c cell parameter compared with the published one due to the incorporation of the partial occupancy water molecule. The title compound crystallizes in the tetragonal chiral space group P41212; the neutral [MnIV(C12H15NO5)2] molecule is situated on a crystallographic C 2 axis. The overall geometry about the central manganese ion is octahedral with an N2O4 core; each ligand acts as a meridional ONO donor. The coordination environment of MnIV at 100 K displays a difference in one of the two Mn-O bond lengths, compared with the room-temperature structure. In the crystal, the neutral molecules are stacked in a helical fashion along the c-axis direction.
Original languageEnglish
Pages (from-to)1307-1310
JournalActa Crystallographica Section E: Crystallographic Communications
Volume71
DOIs
Publication statusPublished - 2015

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Manganese
Hydrates
hydrates
manganese
Crystal structure
crystal structure
Molecules
molecules
manganese ions
Bond length
room temperature
Ligands
Ions
Temperature
Crystals
ligands
Geometry
Water
geometry
cells

Cite this

@article{1035e51c991048f4a9357e8dbafa606c,
title = "Crystal structure of bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) 0.39-hydrate",
abstract = "The title compound, [Mn(C12H15NO5)2]·0.39H2O, is a 0.39 hydrate of the isostructural complex bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) that has previously been reported by Back, Oliveira, Canabarro & Iglesias [Z. Anorg. Allg. Chem. (2015), 641, 941-947], based on room-temperature data. The current structure that was determined at 100 K reveals a lengthening of the c cell parameter compared with the published one due to the incorporation of the partial occupancy water molecule. The title compound crystallizes in the tetragonal chiral space group P41212; the neutral [MnIV(C12H15NO5)2] molecule is situated on a crystallographic C 2 axis. The overall geometry about the central manganese ion is octahedral with an N2O4 core; each ligand acts as a meridional ONO donor. The coordination environment of MnIV at 100 K displays a difference in one of the two Mn-O bond lengths, compared with the room-temperature structure. In the crystal, the neutral molecules are stacked in a helical fashion along the c-axis direction.",
author = "E.A. Buvaylo and O.Y. Vassilyeva and Brian Skelton",
year = "2015",
doi = "10.1107/S2056989015018551",
language = "English",
volume = "71",
pages = "1307--1310",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "INT UNION CRYSTALLOGRAPHY",

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TY - JOUR

T1 - Crystal structure of bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) 0.39-hydrate

AU - Buvaylo, E.A.

AU - Vassilyeva, O.Y.

AU - Skelton, Brian

PY - 2015

Y1 - 2015

N2 - The title compound, [Mn(C12H15NO5)2]·0.39H2O, is a 0.39 hydrate of the isostructural complex bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) that has previously been reported by Back, Oliveira, Canabarro & Iglesias [Z. Anorg. Allg. Chem. (2015), 641, 941-947], based on room-temperature data. The current structure that was determined at 100 K reveals a lengthening of the c cell parameter compared with the published one due to the incorporation of the partial occupancy water molecule. The title compound crystallizes in the tetragonal chiral space group P41212; the neutral [MnIV(C12H15NO5)2] molecule is situated on a crystallographic C 2 axis. The overall geometry about the central manganese ion is octahedral with an N2O4 core; each ligand acts as a meridional ONO donor. The coordination environment of MnIV at 100 K displays a difference in one of the two Mn-O bond lengths, compared with the room-temperature structure. In the crystal, the neutral molecules are stacked in a helical fashion along the c-axis direction.

AB - The title compound, [Mn(C12H15NO5)2]·0.39H2O, is a 0.39 hydrate of the isostructural complex bis(2-{[1,1-bis(hydroxymethyl)-2-oxidoethyl]iminomethyl}-6-methoxyphenolato)manganese(IV) that has previously been reported by Back, Oliveira, Canabarro & Iglesias [Z. Anorg. Allg. Chem. (2015), 641, 941-947], based on room-temperature data. The current structure that was determined at 100 K reveals a lengthening of the c cell parameter compared with the published one due to the incorporation of the partial occupancy water molecule. The title compound crystallizes in the tetragonal chiral space group P41212; the neutral [MnIV(C12H15NO5)2] molecule is situated on a crystallographic C 2 axis. The overall geometry about the central manganese ion is octahedral with an N2O4 core; each ligand acts as a meridional ONO donor. The coordination environment of MnIV at 100 K displays a difference in one of the two Mn-O bond lengths, compared with the room-temperature structure. In the crystal, the neutral molecules are stacked in a helical fashion along the c-axis direction.

U2 - 10.1107/S2056989015018551

DO - 10.1107/S2056989015018551

M3 - Article

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SP - 1307

EP - 1310

JO - Acta Crystallographica. Section E: Structure Reports Online

JF - Acta Crystallographica. Section E: Structure Reports Online

SN - 1600-5368

ER -