Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Y. He; J. Shang; Q. Gu; Gang Li; J. Li; R. Singh; P. Xiao; P.A. Webley

doi:10.1039/c5cc05867h

Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Y. He, J. Shang, Q. Gu, Gang Li, J. Li, R. Singh, P. Xiao, P.A. Webley

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Abstract

© 2015 The Royal Society of Chemistry. We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

Original language	English
Pages (from-to)	14716-14719
Journal	Chemical Communications
Volume	51
Issue number	79
DOIs	https://doi.org/10.1039/c5cc05867h
Publication status	Published - 11 Oct 2015

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10.1039/c5cc05867hLicence: CC BY

Converting 3D rigid metal–organic frameworks 2015 He et alFinal published version, 2.52 MBLicence: CC BY

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title = "Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation",

abstract = "{\textcopyright} 2015 The Royal Society of Chemistry. We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.",

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AU - Li, Gang

AU - Li, J.

AU - Singh, R.

AU - Xiao, P.

AU - Webley, P.A.

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N2 - © 2015 The Royal Society of Chemistry. We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

AB - © 2015 The Royal Society of Chemistry. We report a synthetic strategy for constructing a novel flexible MOF from a rigid parent structure by ligand exchange. This is the first reported study on introducing flexible heterogeneity into a rigid structure via substantial structural rearrangement. The daughter material exhibits enhanced gas separation selectivity compared with the parent.

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DO - 10.1039/c5cc05867h

M3 - Article

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JO - Chemical Communications

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Converting 3D rigid metal-organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation

Abstract

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