Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

I. Ling; Alexandre Sobolev; C.L. Raston

doi:10.1039/c4ce02086c

Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

I. Ling, Alexandre Sobolev, C.L. Raston

School of Molecular Sciences

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

© The Royal Society of Chemistry 2015. Solution mediated organization of p-sulfonatocalix[4]arene, benzyltriphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer.

Original language	English
Pages (from-to)	1526-1530
Journal	CrystEngComm
Volume	17
Issue number	7
Early online date	20 Jan 2015
DOIs	https://doi.org/10.1039/c4ce02086c
Publication status	Published - Feb 2015

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abstract = "{\textcopyright} The Royal Society of Chemistry 2015. Solution mediated organization of p-sulfonatocalix[4]arene, benzyltriphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer. ",

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AU - Sobolev, Alexandre

AU - Raston, C.L.

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N2 - © The Royal Society of Chemistry 2015. Solution mediated organization of p-sulfonatocalix[4]arene, benzyltriphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer.

AB - © The Royal Society of Chemistry 2015. Solution mediated organization of p-sulfonatocalix[4]arene, benzyltriphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer.

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DO - 10.1039/c4ce02086c

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SN - 1466-8033

IS - 7

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Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

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