Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

I. Ling, Alexandre Sobolev, C.L. Raston

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Abstract

© The Royal Society of Chemistry 2015. Solution mediated organization of p-sulfonatocalix[4]arene, benzyltriphenylphosphonium cations, and bis(triethylammoniomethyl)-benzene dications in the solid state results in the ammonium dications preferentially binding in the cavities of two opposing calixarenes which take on a -3 charge, with the phosphonium cations arranged in a separate 2D sheet relative to the calixarene bilayer.
Original languageEnglish
Pages (from-to)1526-1530
JournalCrystEngComm
Volume17
Issue number7
Early online date20 Jan 2015
DOIs
Publication statusPublished - Feb 2015

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